[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(1-isopropyl-3-methylimidazolin-2-ylidene)rhodium(I) tetrafluoridoborate

被引：2

作者：

Nichol, Gary S. ^{[1
]}

Rajaseelan, Jonathan ^{[2
]}

Walton, David P. ^{[3
]}

Rajaseelan, Edward ^{[3
]}

机构：

[1] Univ Arizona, Dept Chem & Biochem, Tucson, AZ 85716 USA

[2] Lancaster Country Day Sch, Lancaster, PA 17603 USA

[3] Millersville Univ Pennsylvania, Dept Chem, Millersville, PA 17551 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

美国国家科学基金会;

关键词：

N-HETEROCYCLIC CARBENES; TRANSFER HYDROGENATION; IRIDIUM COMPLEXES; RHODIUM;

D O I：

10.1107/S1600536811049890

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4)(-) anion are both bisected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general positions. In the crystal, two unique C-H center dot center dot center dot F hydrogen-bonding interactions are present, which involve both imidazolin-2-ylidene H atoms. They form two separate C(5) motifs, the combination of which is a rippled hydrogen-bonded sheet structure in the ab plane.

引用

页码：M1860 / U1411

页数：11

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