Hydrogen Production through Ethanol Steam Reforming on Conducting Heating Alumite Catalysts

被引:2
作者
Nguyen, Ha Thi Khanh [1 ]
Guo, Yu [1 ]
Kawachi, Hideki [1 ]
Sakurai, Makoto [1 ]
Kameyama, Hideo [1 ]
机构
[1] Tokyo Univ Agr & Technol, Dept Chem Engn, Koganei, Tokyo 1848588, Japan
关键词
Ethanol Steam Reforming; Non-Equilibrium System; Nickel; Alumite Catalyst; CO(2) Absorbent; LITHIUM ZIRCONATE;
D O I
10.1252/jcej.10we269
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The aim of this research is to investigate a hydrogen production system using low concentration of ethanol derived from biomass fermentation-renewable materials. By using a non-equilibrium box reactor containing CO(2) absorption agent and alumite catalyst in plate type, CO(2) and CO can be removed from the reaction field, without CO converting and dividing reactors. Due to insertion of CO(2) absorbent, it helped to build up hydrogen selectivity and decrease carbon monoxide formation. First, the support method of the alumite catalysts is studied to increase the durability of the catalysts and prevent carbon formation. The durability of the CO(2) absorption agent is also studied to improve the use times and prevent abrasion phenomenon. Then, the amount of hydrogen that is needed to feed in the 1 kW class household fuel cell is assumed. From these conditions, the required catalysts and CO(2) absorbent are computed. Subsequently, a box reactor is designed in order to appropriately introduce these plates, from which calculation of the reactor volume is performed.
引用
收藏
页码:809 / 815
页数:7
相关论文
共 11 条
[1]   Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications [J].
Breen, JP ;
Burch, R ;
Coleman, HM .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (01) :65-74
[2]   Hydrogen production by auto-thermal reforming of ethanol on Rh/Al2O3 catalyst [J].
Cavallaro, S ;
Chiodo, V ;
Vita, A ;
Freni, S .
JOURNAL OF POWER SOURCES, 2003, 123 (01) :10-16
[3]   Ethanol steam reforming on Rh/Al2O3 catalysts [J].
Cavallaro, S .
ENERGY & FUELS, 2000, 14 (06) :1195-1199
[4]   Ethanol oxidative steam reforming over Ni-based catalysts [J].
Fierro, V ;
Akdim, O ;
Provendier, H ;
Mirodatos, C .
JOURNAL OF POWER SOURCES, 2005, 145 (02) :659-666
[5]   Current status of hydrogen production techniques by steam reforming of ethanol: A review [J].
Haryanto, A ;
Fernando, S ;
Murali, N ;
Adhikari, S .
ENERGY & FUELS, 2005, 19 (05) :2098-2106
[6]  
Kameyama H, 1996, Japanese Patent, Patent No. [2,528,701, 2528701]
[7]   Dual-ion conducting lithium zirconate-based membranes for high temperature CO2 separation [J].
Kawamura, H ;
Yamaguchi, T ;
Nair, BN ;
Nakagawa, K ;
Nakao, S .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2005, 38 (05) :322-328
[8]  
*NEDO, 2007, BASE TECHNOLOGY DEV
[9]  
Tran T. P., 2004, P 10 APPCHE C KIT JA
[10]   Kinetics of carbon dioxide sorption on potassium-doped lithium zirconate [J].
Xiong, RT ;
Ida, J ;
Lin, YS .
CHEMICAL ENGINEERING SCIENCE, 2003, 58 (19) :4377-4385