Self-healing anticorrosion coatings based on pH-sensitive polyelectrolyte/inhibitor sandwichlike nanostructures

被引:283
作者
Andreeva, Daria V. [1 ]
Fix, Dmitri [1 ]
Moehwald, Helmuth [1 ]
Shchukin, Dmitry G. [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany
关键词
D O I
10.1002/adma.200800705
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An anticorrosion layer of a smart polymer coating is developed. The nature and properties of the coating simultaneously provide three mechanisms of corrosion protection: passivation of the metal degradation by controlled release of an inhibitor, buffering of pH changes at the corrosive area by polyelectrolyte layers, and self-curing of the film defects due to the mobility of the polyelectrolyte constituents in the layer-by-layer assembly.
引用
收藏
页码:2789 / +
页数:7
相关论文
共 32 条
[1]  
Brooman E., 2002, Metal Finishing, V100, P42
[2]  
Brooman E. W., 2002, MET FINISH, V100, P104, DOI DOI 10.1016/S0026-0576(02)80446-9
[3]   Polydimethylsiloxane-based self-healing materials [J].
Cho, SH ;
Andersson, HM ;
White, SR ;
Sottos, NR ;
Braun, PV .
ADVANCED MATERIALS, 2006, 18 (08) :997-+
[4]   Inhibitory action of 8-hydroxyquinoline on the copper corrosion process [J].
Cicileo, GP ;
Rosales, BM ;
Varela, FE ;
Vilche, JR .
CORROSION SCIENCE, 1998, 40 (11) :1915-1926
[5]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[6]   Fast ion conduction in layer-by-layer polymer films [J].
DeLongchamp, DM ;
Hammond, PT .
CHEMISTRY OF MATERIALS, 2003, 15 (05) :1165-1173
[7]   High-contrast electrochromism from layer-by-layer polymer films [J].
DeLongchamp, DM ;
Kastantin, M ;
Hammond, PT .
CHEMISTRY OF MATERIALS, 2003, 15 (08) :1575-1586
[8]   Swelling and smoothing of polyelectrolyte multilayers by salt [J].
Dubas, ST ;
Schlenoff, JB .
LANGMUIR, 2001, 17 (25) :7725-7727
[9]   Corrosion control using polyelectrolyte multilayers [J].
Farhat, TR ;
Schlenoff, JB .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (04) :B13-B15
[10]   Ion transport and equilibria in polyelectrolyte multilayers [J].
Farhat, TR ;
Schlenoff, JB .
LANGMUIR, 2001, 17 (04) :1184-1192