Synthesis of 3,3′-bisindoles via demethylenation

被引：5

作者：

Chen, Hui ^{[1
]}

Cui, Ranran ^{[1
]}

Zhang, Yahui ^{[1
]}

Gao, Yu ^{[1
]}

Chen, Haijun ^{[1
]}

机构：

[1] Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Coll Chem, Fujian Prov Univ, Fuzhou 350116, Fujian, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 19期

基金：

中国国家自然科学基金;

关键词：

N BOND-CLEAVAGE; C-C; PEPTIDE-SYNTHESIS; REAGENTS; DESIGN; AMIDE;

D O I：

10.1039/d2qo01010k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we report the mild and metal-free synthesis of 3,3 '-bisindoles. The transformation proceeds through the removal of the Fmoc group followed by the loss of a methylene unit via C-C and C-N bond cleavage. Notably, this scaffold is suitable for further functionalization and displays interesting photophysical properties both in the solution and solid state, indicating its potential application in organic luminophores.

引用

收藏

页码：5281 / 5284

页数：4

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