Short α/β-peptides as catalysts for intra- and intermolecular aldol reactions

被引：102

作者：

D'Elia, Valerio ^{[1
]}

Zwicknagl, Hans ^{[1
]}

Reiser, Oliver ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93053 Regensburg, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 08期

关键词：

D O I：

10.1021/jo800168h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Short alpha/beta-peptides, containing conformationally restricted cis-beta-aminocyclopropylcarboxylic acid units as turn-inducing elements, have been found to be efficient catalysts for inter- and intramolecular aldol reactions. The tripeptide H-(L)-Pro-triangle-(L)-Pro-OH was identified to perform especially well in homogeneous and heterogeneous aqueous solutions as well as in organic solvents.

引用

页码：3262 / 3265

页数：4

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