Molybdenum-Based Carbon Hybrid Materials to Enhance the Hydrogen Evolution Reaction

被引：51

作者：

Bae, Seo-Yoon ^{[1
]}

Jeon, In-Yup ^{[2
]}

Mahmood, Javeed ^{[1
]}

Baek, Jong-Beom ^{[1
]}

机构：

[1] UNIST, Ctr Dimens Controllable Organ Frameworks, Sch Energy & Chem Engn, 50 UNIST, Ulsan 44919, South Korea

[2] Wonkwang Univ, Dept Chem Engn, 460 Iksandae Ro, Iksan 54538, Jeonbuk, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 69期

基金：

新加坡国家研究基金会;

关键词：

carbon; hybrid; hydrogen evolution reaction; molybdenum; renewable energy; REDUCED GRAPHENE OXIDE; HIGH ELECTROCATALYTIC ACTIVITY; ACTIVE EDGE SITES; HIGHLY EFFICIENT; TUNGSTEN CARBIDE; MOSE2; NANOSHEETS; LOW-COST; MESOPOROUS CARBON; ADVANCED CATALYST; PHOSPHIDE;

D O I：

10.1002/chem.201804140

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen is considered a future energy carrier that could improve energy storage of intermittent solar/wind power to solve energy and environmental problems. Based on such demand, development of electrocatalysts for hydrogen generation has been actively pursued. Although Pt is the most efficient catalyst for the hydrogen evolution reaction (HER), it has limits for widespread application, mainly its low abundance and high cost. Thus, developing an efficient catalyst from non-precious metals that are abundant and inexpensive remains an important challenge to replacement of Pt. Transition metals have been considered possible candidates to replace Pt-based catalysts. In this review, among the transition metals, we focus on recently developed molybdenum-carbon (Mo-C) hybrid materials as electrocatalysts for HER. In particular, the synthesis strategy for Mo-C hybrid electrocatalysts and the role of various carbon nanocomposites in Mo-C hybrid systems are highlighted.

引用

页码：18158 / 18179

页数：22

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