Glassy relaxation and excess wing in mode-coupling theory: The dynamic susceptibility of propylene carbonate above and below Tc

被引:25
作者
Domschke, Markus [1 ]
Marsilius, Mie [1 ]
Blochowicz, Thomas [1 ]
Voigtmann, Thomas [2 ,3 ]
机构
[1] Tech Univ Darmstadt, Inst Festkorperphys, D-64289 Darmstadt, Germany
[2] Deutsch Zentrum Luft & Raumfahrt DLR, Inst Mat Phys Weltraum, D-51170 Cologne, Germany
[3] Univ Konstanz, Zukunftskolleg & Fachbereich Phys, D-78457 Constance, Germany
来源
PHYSICAL REVIEW E | 2011年 / 84卷 / 03期
关键词
LIGHT-SCATTERING; SUPERCOOLED LIQUIDS; NONUNIVERSAL FEATURES; SECONDARY RELAXATIONS; DIELECTRIC RESPONSE; FORMING LIQUIDS; TRANSITION; SPECTROSCOPY; UNIVERSAL; EVOLUTION;
D O I
10.1103/PhysRevE.84.031506
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We explore the possibility of describing experimental susceptibility spectra of the glass former propylene carbonate with a two-component schematic model of mode-coupling theory (MCT) from above the melting point down to temperatures far below the critical temperature of MCT. By introducing a phenomenological time-dependent hopping rate, the spectra are reproduced in the full frequency and temperature range available. Literature data of dielectric susceptibilities and depolarized Brillouin light-scattering spectra are combined with our measurements of photon correlation spectroscopy to cover up to 18 decades in frequency of spectra for two different dynamical variables. A consistent description of all data sets is obtained by adjusting only a few physically motivated parameters. In particular the excess wing or slow beta-relaxation commonly observed in the susceptibility spectra can consistently be modeled as originating from a coupling of the individual experimental probe correlator to the collective density fluctuations.
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页数:12
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共 79 条
  • [1] Reexamination of the evolution of the dynamic susceptibility of the glass former glycerol -: art. no. 011504
    Adichtchev, S
    Blochowicz, T
    Tschirwitz, C
    Novikov, VN
    Rössler, EA
    [J]. PHYSICAL REVIEW E, 2003, 68 (01): : 10 - 115041
  • [2] Anomaly of the nonergodicity parameter and crossover to white noise in the fast relaxation spectrum of a simple glass former -: art. no. 055703
    Adichtchev, SV
    Benkhof, S
    Blochowicz, T
    Novikov, VN
    Rössler, E
    Tschirwitz, C
    Wiedersich, J
    [J]. PHYSICAL REVIEW LETTERS, 2002, 88 (05) : 4
  • [3] LOW-FREQUENCY RAMAN-SPECTROSCOPY OF SUPERCOOLED FRAGILE LIQUIDS ANALYZED WITH SCHEMATIC MODE-COUPLING MODELS
    ALBASIMIONESCO, C
    KRAUZMAN, M
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (16) : 6574 - 6585
  • [4] AlbaSimionesco C, 1996, J RAMAN SPECTROSC, V27, P715, DOI 10.1002/(SICI)1097-4555(199610)27:10<715::AID-JRS32>3.0.CO
  • [5] 2-6
  • [6] FAR IR-SPECTRA AND HEAT-CAPACITIES FOR PROPYLENE CARBONATE AND PROPYLENE-GLYCOL, AND THE CONNECTION TO THE DIELECTRIC RESPONSE FUNCTION
    ANGELL, CA
    BOEHM, L
    OGUNI, M
    SMITH, DL
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 1993, 56 : 275 - 286
  • [7] Dynamic Arrest in Multicomponent Glass-Forming Alloys
    Bartsch, Alexander
    Raetzke, Klaus
    Meyer, Andreas
    Faupel, Franz
    [J]. PHYSICAL REVIEW LETTERS, 2010, 104 (19)
  • [8] DYNAMICS OF SUPERCOOLED LIQUIDS AND THE GLASS-TRANSITION
    BENGTZELIUS, U
    GOTZE, W
    SJOLANDER, A
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1984, 17 (33): : 5915 - 5934
  • [9] Anomaly of the rotational nonergodicity parameter of glass formers probed by high field electron paramagnetic resonance
    Bercu, V.
    Martinelli, M.
    Massa, C. A.
    Pardi, L. A.
    Roessler, E. A.
    Leporini, D.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2008, 129 (08)
  • [10] Bridging the gap between the mode coupling and the random first order transition theories of structural relaxation in liquids
    Bhattacharyya, SM
    Bagchi, B
    Wolynes, PG
    [J]. PHYSICAL REVIEW E, 2005, 72 (03):