Molecular wheel to monocyclic ring transition in boron-carbon mixed clusters C2B6- and C3B5-

被引：34

作者：

Galeev, Timur R. ^{[2
]}

Ivanov, Alexander S. ^{[1
]}

Romanescu, Constantin ^{[3
]}

Li, Wei-Li ^{[3
]}

Bozhenko, Konstantin V. ^{[1
]}

Wang, Lai-Sheng ^{[3
]}

Boldyrev, Alexander I. ^{[2
]}

机构：

[1] Peoples Friendship Univ Russia, Dept Phys & Colloid Chem, Moscow 117198, Russia

[2] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

[3] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2011年 / 13卷 / 19期

基金：

美国国家科学基金会;

关键词：

PHOTOELECTRON-SPECTROSCOPY; PLANAR; STABILITY;

D O I：

10.1039/c1cp20359b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this joint experimental and theoretical work we present a novel type of structural transition occurring in the series of CxB8-x- (x = 1-8) mixed clusters upon increase of the carbon content from x = 2 to x = 3. The wheel to ring transition is surprising because it is rather planar-to-linear type of transition to be expected in the series since B-8, B-8(-), B-8(2-) and CB7- are known to possess wheel-type global minimum structures while C-8 is linear.

引用

页码：8805 / 8810

页数：6

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