Synthesis and crystal structure of a one-dimensional chain cadmium coordination polymer bridged through 1,2-bis(imidazol-1-yl)ethane

被引：4
|
作者：
Zhang, Yuping [1 ]
Wang, Liyan [1 ]
Wang, Shouwu [1 ]
Li, Baolong [2 ]
Zhang, Yong [1 ]
机构：
[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2008年 / 38卷 / 02期
关键词：
one-dimensional chain; cadmium(II) complex; bis(imidazole) flexible ligand; hydroxybenzoate; coordination polymer;
D O I：
10.1007/s10870-007-9265-y
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The cadmium(II) complex [Cd(phba)(2)(bim)(H2O)(2)](n) (1) (phba = 4-hydroxybenzoate, bim = 1,2-bis(imidazol-1-yl)ethane) has been synthesized and structurally characterized by X-ray diffraction analysis. It crystallizes in the monoclinic space group C2/c, a = 23.820(4) angstrom, b = 9.5331(14) angstrom, c = 11.1086(19) angstrom, beta = 111.519(4)degrees, V = 2346.7(7) angstrom(3), Z = 4. The coordination geometry of Cd(II) atom is distorted octahedral; it is coordinated by two nitrogen atoms from the imidazole rings of two symmetry-related bim molecules, and four oxygen atoms from two symmetry-related phba anions and two water molecules. The Cd(II) atoms are bridged by bim molecules to form a one-dimensional chain.
引用
收藏
页码：81 / 84
页数：4
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