Liquid-liquid equilibrium for tert-amyl ethyl ether plus methanol plus water

被引:8
|
作者
Arce, A [1 ]
Martínez-Ageitos, J [1 ]
Rodríguez, O [1 ]
Soto, A [1 ]
机构
[1] Univ Santiago de Compostela, Dept Chem Engn, E-15706 Santiago, Spain
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D O I
10.1021/je0003344
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid equilibrium data for tert-amyl ethyl ether + methanol + water were measured experimentally at (298.15, 308.15, and 318.15) K, and correlated with the NRTL and UNIQUAC equations. The correlation was made to each temperature and for the three temperatures simultaneously. The best results were found with the UNIQUAC and NRTL (alpha = 0.1), respectively. Data prediction was carried out using the UNIFAC method, but results were not quantitative.
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页码:557 / 561
页数:5
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