Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

被引：0
|
作者：
Niizeki, Ryotaro [1 ]
Higashida, Kosuke [1 ,2 ]
Mejri, Emna [1 ]
Sawamura, Masaya [1 ,2 ]
Shimizu, Yohei [1 ,2 ]
机构：
[1] Hokkaido Univ, Fac Sci, Dept Chem, Kita Ku, Kita 10 Nishi 8, Sapporo, Hokkaido 0600810, Japan
[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21 Nishi 10, Sapporo, Hokkaido 0010021, Japan
来源：
SYNLETT | 2022年 / 33卷 / 03期
关键词：
gold(III) complexes; ligands; pincer complexes; catalysts; multicomponent reactions; chiral complexes; EFFICIENT CATALYSTS; PROPARGYLAMINES; GOLD; AMINES;
D O I：
10.1055/a-1673-9236
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne.
引用
收藏
页码：288 / 292
页数：5
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