Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

被引：0
|
作者：
Niizeki, Ryotaro [1 ]
Higashida, Kosuke [1 ,2 ]
Mejri, Emna [1 ]
Sawamura, Masaya [1 ,2 ]
Shimizu, Yohei [1 ,2 ]
机构：
[1] Hokkaido Univ, Fac Sci, Dept Chem, Kita Ku, Kita 10 Nishi 8, Sapporo, Hokkaido 0600810, Japan
[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21 Nishi 10, Sapporo, Hokkaido 0010021, Japan
来源：
SYNLETT | 2022年 / 33卷 / 03期
关键词：
gold(III) complexes; ligands; pincer complexes; catalysts; multicomponent reactions; chiral complexes; EFFICIENT CATALYSTS; PROPARGYLAMINES; GOLD; AMINES;
D O I：
10.1055/a-1673-9236
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne.
引用
收藏
页码：288 / 292
页数：5
相关论文
共 50 条
  • [21] Catalytic studies of cyclometalated gold(III) complexes and their related UiO-67 MOF
    Levchenko, Volodymyr A.
    Siah, Huey-San Melanie
    Oien-Odegaard, Sigurd
    Kaur, Gurpreet
    Fiksdahl, Anne
    Tilset, Mats
    MOLECULAR CATALYSIS, 2020, 492 (492)
  • [22] Synthesis and characterization of novel gold(III) complexes with polydentate N-donor ligands based on the pyridine and triazole heterocycles
    Bortoluzzi, Marco
    Scrivanti, Alberto
    Reolon, Andrea
    Amadio, Emanuele
    Bertolasi, Valerio
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 33 : 82 - 85
  • [23] Pyridine vs. Thiazole in Cyclometalated N C N Ni(II) Complexes
    Kletsch, Lukas
    Jordan, Rose
    Strippel, Julian
    Vicic, David A.
    Klein, Axel
    INORGANICS, 2025, 13 (02)
  • [24] Synthesis, structures, and antimalarial activities of some silver(I), gold(I) and gold(III) complexes involving N-heterocyclic carbene ligands
    Hemmert, Catherine
    Fabie, Aymeric
    Fabre, Aude
    Benoit-Vical, Francoise
    Gornitzka, Heinz
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2013, 60 : 64 - 75
  • [25] Synthesis and structure of gold(III) complexes of asymmetric dithiolene ligands
    Tunney, JM
    Blake, AJ
    Davies, ES
    McMaster, J
    Wilson, C
    Garner, CD
    POLYHEDRON, 2006, 25 (02) : 591 - 598
  • [26] Photocatalytic Reduction of CO2 into CO with Cyclometalated Pt(II) Complexes of N∧C∧N Pincer Dipyridylbenzene Ligands: A DFT Study
    Sarantou, Antonia
    Tsipis, Athanassios
    MOLECULES, 2024, 29 (02):
  • [27] Synthesis, characterization, and reactivity of Cp*Rh(III) complexes having functional N,O chelate ligands
    Munjanja, Lloyd
    Yuan, Hongmei
    Brennessel, William W.
    Jones, William D.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 847 : 28 - 32
  • [28] Comparative Study of C∧N and N∧C Type Cyclometalated Ruthenium Complexes with a NAD+/NADH Function
    Padhi, Sumanta Kumar
    Fukuda, Ryoichi
    Ehara, Masahiro
    Tanaka, Koji
    INORGANIC CHEMISTRY, 2012, 51 (15) : 8091 - 8102
  • [29] Dinuclear gold(I) and gold(III) complexes of bridging functionalized bis(N-heterocyclic carbene) ligands: synthesis, structural, spectroscopic and electrochemical characterizations
    Dominique, Francois Jean-Baptiste dit
    Gornitzka, Heinz
    Sournia-Saquet, Alix
    Hemmert, Catherine
    DALTON TRANSACTIONS, 2009, (02) : 340 - 352
  • [30] Synthesis of substituted (N,C) and (N,C,C) Au(iii) complexes: the influence of sterics and electronics on cyclometalation reactions
    Hylland, Knut T.
    Schmidtke, Inga L.
    Wragg, David S.
    Nova, Ainara
    Tilset, Mats
    DALTON TRANSACTIONS, 2022, 51 (13) : 5082 - 5097
12345