Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

被引：0

作者：

Niizeki, Ryotaro ^{[1
]}

Higashida, Kosuke ^{[1
,2
]}

Mejri, Emna ^{[1
]}

Sawamura, Masaya ^{[1
,2
]}

Shimizu, Yohei ^{[1
,2
]}

机构：

[1] Hokkaido Univ, Fac Sci, Dept Chem, Kita Ku, Kita 10 Nishi 8, Sapporo, Hokkaido 0600810, Japan

[2] Hokkaido Univ, Inst Chem React Design & Discovery WPI ICReDD, Kita Ku, Kita 21 Nishi 10, Sapporo, Hokkaido 0010021, Japan

来源：

SYNLETT | 2022年 / 33卷 / 03期

关键词：

gold(III) complexes; ligands; pincer complexes; catalysts; multicomponent reactions; chiral complexes; EFFICIENT CATALYSTS; PROPARGYLAMINES; GOLD; AMINES;

D O I：

10.1055/a-1673-9236

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of neutral C,N,N Au(III) complexes were synthesized with N -(8-quinolinyl)benzamide derivatives or chiral N -[2-(1,3-oxazolin-2-yl)phenyl]benzamide derivatives. The convenient synthesis method for the amide ligands, together with their operationally simple complexation by direct C-H auration, permitted changes to both the steric and electronic properties of Au(III) complexes for promoting the catalytic three-component couplings of an aldehyde, an amine, and an alkyne.

引用

页码：288 / 292

页数：5

共 50 条

[1] New Variations on the Theme of Gold(III) C∧N∧N Cyclometalated Complexes as Anticancer Agents: Synthesis and Biological Characterization
Carboni, Silvia
Zucca, Antonio
Stoccoro, Sergio
Maiore, Laura
Arca, Massimiliano
Ortu, Fabrizio
Artner, Christian
Keppler, Bernhard K.
Meier-Menches, Samuel M.
Casini, Angela
Cinellu, Maria Agostina
INORGANIC CHEMISTRY, 2018, 57 (23) : 14852 - 14865
[2] Hard to Handle: Extremely Labile Hydrido Nickel(II) Complexes of Cyclometalated C⊥N⊥N and N⊥C⊥N Ligands
Kletsch, Lukas
Payen, Leo
Fiorentino, Antonio
Blom, Burgert
Romano, Dario
Hoerner, Gerald
Klein, Axel
ORGANOMETALLICS, 2023, 42 (16) : 2206 - 2215
[3] Synthesis, C-N cleavage and photoluminescence of gold(III) isocyanide complexes
Rosca, Dragos-Adrian
Fernandez-Cestau, Julio
Romanov, Alexander S.
Bochmann, Manfred
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 792 : 117 - 122
[4] The synthesis and photophysical studies of cyclometalated Pt(II) complexes with C,N,N-ligands containing imidazolyl donors
Ho, Yu-Man
Koo, Chi-Kin
Wong, Ka-Leung
Kong, Hoi-Kuan
Chan, Chris Tsz-Leung
Kwok, Wai-Ming
Chow, Cheuk-Fai
Lam, Michael Hon-Wah
Wong, Wai-Yeung
DALTON TRANSACTIONS, 2012, 41 (06) : 1792 - 1800
[5] Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes
Tlahuext-Aca, Adrian
Hopkinson, Matthew N.
Daniliuc, Constantin G.
Glorius, Frank
CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (33) : 11587 - 11592
[6] (P∧N∧C) Ligands to Stabilize Gold(III): A Straightforward Access to Hydroxo, Formate, and Hydride Complexes
Martin, Jaime
Schorgenhumer, Johannes
Biedrzycki, Michal
Nevado, Cristina
INORGANIC CHEMISTRY, 2024, 63 (18) : 8390 - 8396
[7] Gold(III) Carboxylate Complexes with N, N-Chelating Ligands: Synthesis, Structure, and Features of IR Spectra
Akhmadullina, Nailya S.
Borissova, Aleksandra O.
Garbuzova, Irina A.
Retivov, Vasiliy M.
Sandu, Roman A.
Kargin, Yuri F.
Shishilov, Oleg N.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (02): : 392 - 397
[8] Luminescent (N∧C∧C) Gold(III) Complexes: Stabilized Gold(III) Fluorides
Kumar, Roopender
Linden, Anthony
Nevado, Cristina
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (48) : 14287 - 14290
[9] Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation
Martin, Jaime
Gomez-Bengoa, Enrique
Genoux, Alexandre
Nevado, Cristina
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (20)
[10] Cyclometalated Gold(III) Complexes: Synthesis, Reactivity, and Physicochemical Properties
Kumar, Roopender
Nevado, Cristina
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (08) : 1994 - 2015

← 1 2 3 4 5 →