Chromium-Catalyzed Regioselective Kumada Arylative Cross-Coupling of C(aryl)-O Bonds with a Traceless Activation Strategy

被引：24
作者：
Fan, Fei [1 ]
Tang, Jinghua [1 ]
Luo, Meiming [1 ]
Zeng, Xiaoming [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 83卷 / 21期
基金：
中国国家自然科学基金;
关键词：
C-O BOND; CARBON-OXYGEN BOND; ARYL 2-PYRIDYL ETHERS; GRIGNARD-REAGENTS; ARYLBORONIC ACIDS; HETEROATOM BONDS; AROMATIC KETONES; ROOM-TEMPERATURE; DIRECTING GROUP; METHYL ETHERS;
D O I：
10.1021/acs.joc.8b02104
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report here the chromium-catalyzed regioselective Kumada arylative cross-coupling of C(aryl)-O bonds at ambient temperature. By using a simple and low-cost chromium(II) chloride salt as a precatalyst, accompanied by a 2-pyridyl ligation, the catalytic cleavage and arylative coupling of C(aryl)-O bonds were achieved with a traceless activation strategy, overcoming the regioselectivity obstacle when several C-O bonds coexist in the Kumada coupling system.
引用
收藏
页码：13549 / 13559
页数：11
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