(Acetonitrile)bis(1,10-phenanthroline) copper(II)bis( perchlorate)

被引：4
|
作者：
Serb, Mihaela-Diana
Calmuschi-Cula, Beatrice
Dumitru, Florina
Dols, Thomas
Englert, Ulli
Guran, Cornelia
机构：
[1] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany
[2] Univ Politehn Bucuresti, Dept Inorgan Chem, Bucharest 011061, Romania
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
single-crystal X-ray study; T=130 K; Mean sigma(C; C)=0.003 angstrom; disorder in main residue; R factor=0.049; wR factor=0.109; data-to-parameter ratio=16.1;
D O I：
10.1107/S1600536807015036
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Cu(C12H8N2)(2)(CH3CN)](ClO4)(2), the five-coordinate Cu-II ion has a distorted square-pyramidal coordination geometry composed of five N atoms, four from two bidentate chelating phenanthroline ligands and one from acetonitrile. The acetonitrile molecule and the Cu atom are situated on a crystallographic twofold rotation axis.
引用
收藏
页码：M1292 / M1293
页数：2
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