Photoredox Catalysis of Visible-light-responsive Divacant Lacunary Silicotungstate for Selective Reduction of Aldehydes

被引：9

作者：

Suzuki, Kosuke ^{[1
]}

Yamaguchi, Kazuya ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 09期

关键词：

Polyoxometalate; Photoredox catalysis; Selective reduction; VERLEY-TYPE REDUCTION; TITANIUM-DIOXIDE; REDOX POTENTIALS; ELECTRON; COMPLEXES; CHEMISTRY; OLEFINS;

D O I：

10.1246/cl.170577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report photoredox catalysis of a visible-light-responsive divacant lacunary silicotungstate TBA(4)H(4)[gamma-SiW10O36] (I, TBA: tetra-n-butylammonium) for the selective reduction of aldehydes. In particular, the catalytic activity of I was significantly enhanced by controlling the redox potential by deprotonation using TBAOH. The reduction of various aromatic aldehydes selectively proceeded to afford the corresponding alcohols using ethanol as the reducing agent by photoirradiation (lambda > 385 nm).

引用

页码：1379 / 1382

页数：4

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