Straightforward Generation of Helical Chirality Driven by a Versatile Heteroscorpionate Ligand: Self-Assembly of a Metal Helicate by Using CH-π Interactions

被引：30

作者：

Otero, Antonio ^{[1
]}

Lara-Sanchez, Agustin ^{[1
]}

Fernandez-Baeza, Juan ^{[1
]}

Alonso-Moreno, Carlos ^{[1
]}

Tejeda, Juan ^{[1
]}

Castro-Osma, Jose A. ^{[1
]}

Marquez-Segovia, Isabel ^{[1
]}

Sanchez-Barba, Luis F. ^{[2
]}

Rodriguez, Ana M. ^{[1
]}

Gomez, M. Victoria ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, E-13071 Ciudad Real, Spain

[2] Univ Rey Juan Carlos, Dept Quim Inorgan & Analit, Madrid 28933, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 29期

关键词：

aluminum; CH-pi interactions; chirality; heteroscorpionate ligands; self-assembly; RING-OPENING POLYMERIZATION; COORDINATION CHEMISTRY; COMPLEXES; METHANE; DESIGN;

D O I：

10.1002/chem.201000694

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Figure Presented In a twist: The synthesis of novel architectures, through the use of versatile heteroscorpionate ligands, was developed that allows helical chirality in aluminium complexes (see figure). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8615 / 8619

页数：5

共 37 条

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