Shear thickening of Laponite suspensions with poly(ethylene oxide)

被引:18
|
作者
Fall, Abdoulaye [1 ,2 ]
Bonn, Daniel [1 ,3 ]
机构
[1] Univ Amsterdam, Van der Waals Zeeman Inst, NL-1018 XE Amsterdam, Netherlands
[2] Univ Bordeaux 1, CNRS, UMR Rhodia, Lab Futur, F-33608 Pessac, France
[3] Ecole Normale Super, Lab Phys Stat, F-75231 Paris 05, France
关键词
ANGLE NEUTRON-SCATTERING; STATIC LIGHT-SCATTERING; POLYMER-CLAY SOLUTIONS; RHEOLOGICAL BEHAVIOR; FLOW-BIREFRINGENCE; MOLECULAR-WEIGHT; COLLOIDAL DISKS; DRAG REDUCTION; PEO MIXTURES; SHAKE-GELS;
D O I
10.1039/c2sm07089h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the effect of addition of polyethylene oxide (PEO) on the rheological behavior of suspensions of Laponite. Experiments were performed on mixtures of PEO and Laponite at different concentrations. These mixtures can exhibit very strong shear thickening behavior: under shear, the suspension can become a yield stress material sufficiently strong to support its own weight. Depending on the polymer concentration, we observe continuous or discontinuous shear thickening mechanisms; it is the discontinuous shear thickening that leads to the formation of yield stress materials.
引用
收藏
页码:4645 / 4651
页数:7
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