RETRACTED: Supramolecular self-assembly of protoporphyrin IX amphiphiles into worm-like and particular aggregates (Retracted article. See FEB, 2023)

被引:16
作者
Bhosale, Sheshanath V. [1 ]
Kalyankar, Mohan B. [2 ]
Bhosale, Sidhanath V. [2 ]
Patil, Sudhakar G. [1 ]
Lalander, Cecilia H. [1 ]
Langford, Steven J. [1 ]
Nalage, Santosh V. [2 ]
机构
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[2] N Maharashtra Univ, Dept Organ Chem, Jalgaon 425001, India
基金
澳大利亚研究理事会;
关键词
protoporphyrin IX; self-assembly; nanoaggregates; AFM; OCTOPUS-PORPHYRIN; VESICLES; MICROSTRUCTURE; BEHAVIOR; BINDING; FIBERS;
D O I
10.1080/10610278.2010.523115
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A protoporphyrin IX amphiphile bearing hydrophobic-hydrophilic functional regions was synthesised by coupling protoporphyrin IX with methoxytriethylene glycol using (3-(dimethylamino)propyl)ethyl carbodiimide hydrochloride/1-hydroxybenzotriazole followed by a double-cross metathesis with 1-undecene using second-generation Grubb's catalyst. The self-assembling behaviour of the amphiphile in varying concentration of CHCl3/MeOH was investigated, with well-defined nanostructures described as worm-like fibrils and particular aggregates being formed in 1:1 and 1:9 v/v of MeOH/CHCl3, respectively.
引用
收藏
页码:263 / 268
页数:6
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