Alkane-oxidizing metalloenzymes in the carbon cycle

被引：57
作者：
Austin, Rachel Narehood [1 ]
Groves, John T. [2 ]
机构：
[1] Bates Coll, Dept Chem, Lewiston, ME 04240 USA
[2] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
来源：
METALLOMICS | 2011年 / 3卷 / 08期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
CHAIN N-ALKANES; SUBSTRATE RADICAL INTERMEDIATE; ACINETOBACTER SP M-1; PARTICULATE METHANE MONOOXYGENASE; METHYLOCOCCUS-CAPSULATUS BATH; SULFATE-REDUCING BACTERIUM; H BOND ACTIVATION; GULF-OF-MEXICO; PSEUDOMONAS-OLEOVORANS; XYLENE MONOOXYGENASE;
D O I：
10.1039/c1mt00048a
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This review examines the metalloenzymes that catalyze the oxidation of alkanes in the environment. The focus of the review is on what is known about the relative abundances of these metalloenzymes, their metal ion requirements, and their reaction mechanisms. The relative significance of these reactions in the global transformation of alkanes is discussed.
引用
收藏
页码：775 / 787
页数：13
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