Silver(I) complexes of bis[2-(diphenylphosphino)phenyl] ether

被引：15

作者：

Balakrishna, Maravanji S. ^{[1
]}

Venkateswaran, Ramalingam ^{[1
]}

Mobin, Shaikh M. ^{[2
]}

机构：

[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India

[2] Indian Inst Technol, Natl Single Crystal Xray Diffract Facil, Bombay 400076, Maharashtra, India

来源：

POLYHEDRON | 2008年 / 27卷 / 03期

关键词：

mixed-ligand silver complexes; DPEphos; 2,2 '-bipyridine; chelating complexes; crystal structures;

D O I：

10.1016/j.poly.2007.11.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of AgOTf in dichloromethane with bis(2-(diphenylphosphino)phenyl) ether (DPEphos) in an equimolar ratio afforded a dinuclear complex [Ag-2(K-2-P,P '-DPEphOS)(2)(mu-OTf)(2)] (1), whereas the similar reaction in a 1:2 molar ratio resulted in the formation of a bis-chelating complex [Ag(K-2-P,P '-DPEphos)(2)][OTf] (2). The silver(I) complex 1 was obtained as a dimer, in which two silver atoms are bridged by two triflate groups to form three adjacent eight-membered spirocyclic rings. The mixed-ligand complex [Ag(K-2-P,P '-DPEphos)(2,2 '-bpy)][OTf] (3) was obtained in the reaction of I in dichloromethane with 2,2 '-bipyridine. The crystal structures of complexes 1 3 were determined by single crystal X-ray analyses. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：899 / 904

页数：6

共 50 条

[31] Bis[1,2](diphenylphosphino)ethane]silver(I) bis(trifluoroacetato)triphenylstannate(IV)
Chee, CF
Lo, KM
Ng, SW
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M273 - M275
[32] Platinum complexes of (R)-N,N-bis(2-(diphenylphosphino)ethyl)-1-phenyl-ethylamine:: their synthesis and characterisation
Jánosi, L
Kégl, T
Hajba, L
Berente, Z
Kollár, L
INORGANICA CHIMICA ACTA, 2001, 316 (1-2) : 135 - 139
[33] Self-assembly of heteroleptic dinuclear silver(I) complexes bridged by bis(diphenylphosphino)ethyne
Keller, Sarah
Camenzind, Timothy N.
Abraham, Johannes
Prescimone, Alessandro
Haussinger, Daniel
Constable, Edwin C.
Housecroft, Catherine E.
DALTON TRANSACTIONS, 2018, 47 (03) : 946 - 957
[34] Dimeric 1:2 adduct of β,β′-bis(diphenylphosphino)porphyrin with silver(I) chloride
Fujimoto, Keisuke
Yorimitsu, Hideki
Osuka, Atsuhiro
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2015, 19 (1-3) : 171 - 174
[35] N-[2-(diphenylphosphino)phenyl]benzamide
Zhang, Wen-Jie
Chen, Jian-Xin
Li, Zhong-Shui
Li, Ai-Ke
Lin, Xin-Rong
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4016 - U2731
[36] Iron carbonyl complex containing bis[2-(diphenylphosphino)phenyl]ether enhancing efficiency in the palladium-catalyzed Suzuki-Miyaura reaction
Borah, Malabika
Bhattacharyya, Pradip K.
Das, Pankaj
APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (03) : 130 - 134
[37] Similarities and differences between bis[2-(bromomethyl)phenyl] diselenide, bis[2-(chloromethyl)phenyl] diselenide and bis[2-(hydroxymethyl)phenyl] diselenide
Lari, Alberth
Rominger, Frank
Gleiter, Rolf
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : O400 - O403
[38] Cytotoxic activity of Ru(II)/DPEPhos/N,S-mercapto complexes (DPEPhos = bis-[(2-diphenylphosphino)phenyl]ether)
Grawe, Gregory F.
Oliveira, Katia M.
Leite, Celisnolia M.
de Oliveira, Tamires D.
Costa, Analu R.
Moraes, Carlos A. F.
Honorato, Joao
Cominetti, Marcia R.
Castellano, Eduardo E.
Correa, Rodrigo S.
Machado, Sergio P.
Batista, Alzir A.
JOURNAL OF INORGANIC BIOCHEMISTRY, 2023, 244
[39] Structural and electronic properties of luminescent copper(I) halide complexes of bis[2-(diphenylphosphano)phenyl] ether (DPEphos). Crystal structure of [CuCl(DPEphos)(dmpymtH]
Aslanidis, P.
Cox, P. J.
Tsipis, A. C.
DALTON TRANSACTIONS, 2010, 39 (42) : 10238 - 10248
[40] COMPLEXES OF CU(I) HALIDES WITH BIS(DIPHENYLPHOSPHINO)METHANE AND 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE
MARSICH, N
CAMUS, A
CEBULEC, E
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (03): : 933 - &

← 1 2 3 4 5 →