Palladium-catalyzed R(sp3)-Zn/R(sp)-SnBu3 oxidative cross-coupling

被引：18

作者：

Jin, Liqun ^{[1
]}

Zhao, Yingsheng ^{[1
]}

Wang, Haibo ^{[1
]}

Lei, Aiwen ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2008年 / 04期

关键词：

oxidative cross-coupling; transmetalation; organotin reagents; organozinc reagents; palladium;

D O I：

10.1055/s-2007-990863

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel bond formation through oxidative cross-coupling with desyl chloride as the oxidant has been investigated. The coupling can be carried out under mild conditions. The Csp(3)-center carbon was involved even in the presence of a beta-H, and up to 90% of the desired cross-coupling product was obtained with the secondary CSp(3)-center substrate.

引用

页码：649 / 654

页数：6

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