Utilization of Natural Sunlight and Air in the Aerobic Oxidation of Benzyl Halides

被引：216

作者：

Su, Yijin ^{[1
]}

Zhang, Liangren ^{[1
]}

Jiao, Ning ^{[1
,2
]}

机构：

[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomitnet Drugs, Beijing 100191, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 09期

基金：

美国国家科学基金会;

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; MOLECULAR-OXYGEN; PYRIDINIUM SALTS; FINE CHEMICALS; DIOXYGEN; ALKYNES; EFFICIENT; RADICALS; ALCOHOLS;

D O I：

10.1021/ol2002013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel, efficient oxidation of alpha-aryl halogen derivatives to the corresponding alpha-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.

引用

页码：2168 / 2171

页数：4

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