Bis[2-(methylamino)troponato]copper(II)

被引：5
|
作者：
Steyl, Gideon [1 ]
Muller, Theunis J. [1 ]
Roodt, Andreas [1 ]
机构：
[1] Univ Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536810043503
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(C8H8NO)(2)], a strictly square-planar geometry about the Cu-II metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II)complex when compared with a similar bis(troponato) copper(II) complex. pi-pi stacking is observed between the tropolone rings, with interplanar distances of 3.5039 (16) and 3.2933 (15) angstrom, respectively. Additional stabilisation of the structure is accomplished through C-H center dot center dot center dot O hydrogen-bonding interactions.
引用
收藏
页码：M1508 / U276
页数：9
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