Volatile organic compounds absorption in packed column: theoretical assessment of water, DEHA and PDMS 50 as absorbents

被引:21
作者
Biard, Pierre-Francois [1 ]
Couvert, Annabelle [1 ]
Giraudet, Sylvain [1 ]
机构
[1] CNRS, UMR 6226, Ecole Natl Super Chim Rennes, CS 50837, 11 Allee Beaulieu, F-35708 Rennes 7, France
关键词
Absorption; Mass-transfer; Volatile organic compound; DEHA; Silicone oil; MASS-TRANSFER; CHLORINATED VOCS; SILICONE OIL; TOLUENE; LIQUID; COEFFICIENTS; SOLVENTS; HYDRODYNAMICS; CONTACTOR; DILUTION;
D O I
10.1016/j.jiec.2017.10.008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A fixed volume packed column was simulated for the absorption at counter-current of four more or less hydrophobic volatile organic compounds (VOCs) in water and in two heavy organic solvents (PDMS 50, a silicone oil) and DEHA (Bis(2-ethylhexyl) adipate). Reliable values of the mass-transfer coefficients were deduced allowing to calculate the VOCs removal efficiency. Disappointing performances in heavy solvents, lower than 60% for isopropanol and acetone, were computed in a 3 m height column and using mild conditions (atmospheric pressure and a liquid-to-gas mass flow rate ratio around 2). However, toluene removal efficiencies higher than 90% were simulated. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:70 / 78
页数:9
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