Alumina-supported In2O3, Ga2O3 and B2O3 catalysts for lean NOx reduction with dimethyl ether

被引：8

作者：

Erkfeldt, Sara ^{[1
,2
]}

Petersson, Martin ^{[3
]}

Palmqvist, Anders ^{[2
]}

机构：

[1] Volvo Technol Corp, SE-41288 Gothenburg, Sweden

[2] Chalmers, Competence Ctr Catalysis, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden

[3] Volvo Powertrain Corp, Dept 91514, BC2, SE-40508 Gothenburg, Sweden

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2012年 / 117卷

基金：

瑞典研究理事会;

关键词：

Hydrocarbon-SCR; NOx reduction; Alumina; Alternative fuel; Dimethyl ether; Indium; Gallium; Boron; PREPARED GA2O3-AL2O3 CATALYSTS; GALLIUM OXIDE CATALYSTS; ENGINE EXHAUST-GAS; SELECTIVE REDUCTION; GAMMA-ALUMINA; NITRIC-OXIDE; MECHANISTIC ASPECTS; NITROGEN MONOXIDE; EXCESS OXYGEN; DME;

D O I：

10.1016/j.apcatb.2012.01.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alumina-supported In2O3, Ga2O3 and B2O3 were investigated as catalysts for lean NOx reduction with DME as reducing agent and compared to pure Al2O3 and In2O3. The In2O3-promoted alumina catalysts showed the highest NOx conversion at low temperatures, although with a narrow temperature window. Pure In2O3, on the other hand, was inactive for NOx reduction with DME. The Ga2O3- and B2O3-promoted alumina catalysts gave the highest NOx conversion at higher temperatures, showed a temperature window similar to pure alumina, but were less sensitive to H2O inhibition. Possible reasons for these observations are discussed. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：369 / 383

页数：15

共 50 条

[1] In2O3/Al2O3 catalysts for NOx reduction in lean condition
Park, PW
Ragle, CS
Boyer, CL
Balmer, ML
Engelhard, M
McCready, D
JOURNAL OF CATALYSIS, 2002, 210 (01) : 97 - 105
[2] Fluidized-Bed Isobutane Dehydrogenation over Alumina-Supported Ga2O3 and Ga2O3-Cr2O3 Catalysts
Matveyeva, Anna N.
Zaitseva, Nadezhda A.
Maki-Arvela, Paivi
Aho, Atte
Bachina, Anastasia K.
Fedorov, Sergey P.
Murzin, Dmitry Yu.
Pakhomov, Nikolai A.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (03) : 927 - 938
[3] Experimental electronic structure of In2O3 and Ga2O3
Janowitz, Christoph
Scherer, Valentina
Mohamed, Mansour
Krapf, Alica
Dwelk, Helmut
Manzke, Recardo
Galazka, Zbigniew
Uecker, Reinhard
Irmscher, Klaus
Fornari, Roberto
Michling, Marcel
Schmeisser, Dieter
Weber, Justin R.
Varley, Joel B.
Van de Walle, Chris G.
NEW JOURNAL OF PHYSICS, 2011, 13
[4] SYNTHESIS AND CHARACTERIZATION OF GA2O3 AND IN2O3 NANOWIRES
Stafiniak, Andrzej
Prazmowska, Joanna
Korbutowicz, Ryszard
Serafinczuk, Jaroslaw
Paszkiewicz, Regina
ADVANCES IN ELECTRICAL AND ELECTRONIC ENGINEERING, 2019, 17 (02) : 229 - 233
[5] SYSTEMATICS OF EVAPORATION COEFFICIENT AL2O3 GA2O3 IN2O3
BURNS, RP
JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (09): : 3307 - +
[6] An ultraviolet photodetector based on In2O3/β-Ga2O3 heterojunction
Zhang, Yongfeng
Liu, Xinyan
Bi, Zhengyu
Xu, Ruiliang
Chen, Yu
Zhou, Jingran
Ruan, Shengping
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2024, 181
[7] Differences Between Al2O3 and Ag/Al2O3 for Lean Reduction of NOx with Dimethyl Ether
Stefanie Tamm
Hanna H. Ingelsten
Magnus Skoglundh
Anders E. C. Palmqvist
Topics in Catalysis, 2009, 52
[8] Differences Between Al2O3 and Ag/Al2O3 for Lean Reduction of NOx with Dimethyl Ether
Tamm, Stefanie
Ingelsten, Hanna H.
Skoglundh, Magnus
Palmqvist, Anders E. C.
TOPICS IN CATALYSIS, 2009, 52 (13-20) : 1813 - 1816
[9] Metal oxide catalysts for DME steam reforming: Ga2O3 and Ga2O3–Al2O3 catalysts
Thomas Mathew
Yusuke Yamada
Atsushi Ueda
Hiroshi Shioyama
Tetsuhiko Kobayashi
Catalysis Letters, 2005, 100 : 247 - 253
[10] Impregnated and Co-precipitated Pd–Ga2O3, Pd–In2O3 and Pd–Ga2O3–In2O3 Catalysts: Influence of the Microstructure on the CO2 Selectivity in Methanol Steam Reforming
Christoph Rameshan
Harald Lorenz
Marc Armbrüster
Igor Kasatkin
Bernhard Klötzer
Thomas Götsch
Kevin Ploner
Simon Penner
Catalysis Letters, 2018, 148 : 3062 - 3071

← 1 2 3 4 5 →