A highly efficient general synthesis of phosphine-borane complexes

被引：25

作者：

McNulty, J

Zhou, YH

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

[2] Cytec Canada Inc, Niagara Falls, ON L2E 6T4, Canada

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 02期

关键词：

phosphine; phosphine borane;

D O I：

10.1016/j.tetlet.2003.10.145

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general synthesis of phosphine-borane complexes proceeding in high yield in a safe, green process from borane generated in situ from sodium borohydride is described. The procedure also allows simultaneous carbonyl reduction and phosphine-borane formation on air-sensitive bulky phosphine derivatives. (C) 2003 Elsevier Ltd. All rights reserved.

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收藏

页码：407 / 409

页数：3

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