Polymorphism of Amino Acid-Based Dendrons: From Organogels to Microcrystals

被引：23
|
作者：
Kuang, Gui-Chao [1 ,2 ]
Teng, Ming-Jun [1 ,2 ]
Jia, Xin-Ru [1 ,2 ]
Chen, Er-Qiang [1 ,2 ]
Wei, Yen [3 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Minist Educ, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China
[3] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 05期
基金：
中国国家自然科学基金;
关键词：
amino acids; beta sheets; dendrons; polymorphism; self-assembly; DENDRITIC ORGANOGELATORS; GELATION PROPERTIES; SELF-ORGANIZATION; MOLECULAR-WEIGHT; BLOCK DENDRONS; FIBER NETWORK; ARCHITECTURE; BEHAVIOR; GELS; MORPHOLOGY;
D O I：
10.1002/asia.201000529
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There is a delicate balance for a low-weight molecule to behave as a gelator or crystal. The synthesis of two novel amino acid-based naphthalene-dendrons, Nap-G1 and Nap-G2 is described. Both dendrons display polymorphic properties in organic solvents. Nap-G1 developed a fibrous network with beta-sheet architecture in cyclohexane but exhibited a spherulitic network in mixed solvents (chloroform/petroleum ether 1: 5, v/v). On the other hand, Nap-G2 acted as an efficient organogelator in chloroform but formed crystalline fibers in relatively high polarity solvents (such as acetone and methanol). Combinations of characterizations have been employed to study the polymorphism.
引用
收藏
页码：1163 / 1170
页数：8
相关论文
共 50 条
  • [21] Pharmaceutical organogels prepared from aromatic amino acid derivatives
    Bastiat, Guillaume
    Leroux, Jean-Christophe
    JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (23) : 3867 - 3877
  • [22] Plasma amino acid analysis for diagnosis and amino acid-based metabolic networks
    Kimura, Takeshi
    Noguchi, Yasushi
    Shikata, Nahoko
    Takahashi, Mitsuo
    CURRENT OPINION IN CLINICAL NUTRITION AND METABOLIC CARE, 2009, 12 (01): : 49 - 53
  • [23] Polymerization of acrylic monomers with dendrons based on dicarboxylic α-amino acid units
    Girbasova, NV
    Migunova, II
    Raspopova, IR
    Bilibin, AY
    POLYMER SCIENCE SERIES A, 2003, 45 (04) : 320 - 329
  • [24] Biodegradation behavior of segmented polyurethanes prepared from amino acid-based diisocyanate
    Takahara, A
    Hadano, M
    Yamaguchi, T
    Otsuka, H
    Kidoaki, S
    Matsuda, T
    Aoi, K
    Sasaki, S
    Proceedings of 2005 International Conference on Advanced Fibers and Polymer Materials (ICAFPM 2005), Vol 1 and 2: NEW CENTURY , NEW MATERIALS AND NEW LIFE, 2005, : 897 - 901
  • [25] Intrinsic MRI contrast from amino acid-based paramagnetic ionic liquids
    Gehlot, Praveen Singh
    Gupta, Hariom
    Rathore, Mangal Singh
    Khatri, Kusum
    Kumar, Arvind
    MATERIALS ADVANCES, 2020, 1 (06): : 1980 - 1987
  • [26] ATRP from an amino acid-based initiator:: A facile approach for α-functionalized polymers
    Venkataraman, Shrinivas
    Wooley, Karen L.
    MACROMOLECULES, 2006, 39 (26) : 9661 - 9664
  • [27] Chiralα-Amino Acid-Based NMR Solvating Agents
    Nemes, Aniko
    Csoka, Tamas
    Beni, Szabolcs
    Garadi, Zsofia
    Szabo, Denes
    Rabai, Jozsef
    HELVETICA CHIMICA ACTA, 2020, 103 (08)
  • [28] New insight of amino acid-based dialysis solutions
    Park, M. S.
    Choi, S. R.
    Song, Y. S.
    Yoon, S. Y.
    Lee, S. Y.
    Han, D. S.
    KIDNEY INTERNATIONAL, 2006, 70 : S110 - S114
  • [29] Use of amino acid-based polymeric material for isolation of a protein from poison
    Erol, Kadir
    Kose, Kazirn
    Gungunes, Hakan
    Kose, Dursun Ali
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1130 : 753 - 759
  • [30] Effective Cellular Delivery of Antisense Peptide Nucleic Acid by Conjugation to Guanidinylated Diaminobutanoic Acid-Based Peptide Dendrons
    Gabas, Isabel Maicas
    Nielsen, Peter E.
    BIOMACROMOLECULES, 2020, 21 (02) : 472 - 483
12345