Hydrogen-bonded clusters of 1,1′-ferrocenedicarboxylic acid on Au(111) are initially formed in solution

被引：15

作者：

Quardokus, Rebecca C. ^{[1
]}

Wasio, Natalie A. ^{[1
]}

Brown, Ryan D. ^{[1
]}

Christie, John A. ^{[1
]}

Henderson, Kenneth W. ^{[1
]}

Forrest, Ryan P. ^{[1
]}

Lent, Craig S. ^{[2
]}

Corcelli, Steven A. ^{[1
]}

Kandel, S. Alex ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[2] Univ Notre Dame, Dept Elect Engn, Notre Dame, IN 46556 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2015年 / 142卷 / 10期

基金：

美国国家科学基金会;

关键词：

MASS-SPECTROMETRIC ANALYSIS; MOLECULAR ASSOCIATION; ADIABATIC EXPANSION; CARBOXYLIC-ACIDS; TETROLIC ACID; LIQUID JETS; CRYSTAL; SURFACES; DIMER; POLYMORPHISM;

D O I：

10.1063/1.4909517

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low-temperature scanning tunneling microscopy is used to observe self-assembled structures of ferrocenedicarboxylic acid (Fc(COOH)(2)) on the Au(111) surface. The surface is prepared by pulse-deposition of Fc(COOH)(2) dissolved in methanol, and the solvent is evaporated before imaging. While the rows of hydrogen-bonded dimers that are common for carboxylic acid species are observed, the majority of adsorbed Fc(COOH)(2) is instead found in six-molecule clusters with a well-defined and chiral geometry. The coverage and distribution of these clusters are consistent with a random sequential adsorption model, showing that solution-phase species are determinative of adsorbate distribution for this system under these reaction conditions. (C) 2015 AIP Publishing LLC.

引用

页数：7

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