Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting

被引：11

作者：

Benkhaeuser, Christian ^{[1
]}

Luetzen, Arne ^{[1
]}

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 11卷

关键词：

metal complexes; multivalency; self-assembly; self-sorting; supramolecular chemistry; Troger's base; TROGERS BASE; BIS(PYRIDINE) LIGANDS; COORDINATION; COMPLEXES; SYSTEMS; CONSTRUCTION; RECOGNITION; MOLECULES; SELECTION; HELICATE;

D O I：

10.3762/bjoc.11.79

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Troger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal ions these two ligands undergo selective self-assembly into heteroleptic dinuclear metallosupramolecular kites in a high-fidelity social self-sorting manner as evidenced by NMR spectroscopy and mass spectrometry.

引用

页码：693 / 700

页数：8

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