Microwave assisted synthesis of an unusual dinitro phytochemical

被引:12
作者
Bose, AK [1 ]
Ganguly, SN [1 ]
Manhas, MS [1 ]
Srirajan, V [1 ]
Bhattacharjee, A [1 ]
Rumthao, S [1 ]
Sharma, AH [1 ]
机构
[1] Stevens Inst Technol, Dept Chem & Chem Biol, George Barasch Bioorgan Res Lab, Hoboken, NJ 07030 USA
关键词
ipso-substitution; mild nitration; dinitrostyrene; clay-based reactions; phytochemicals; antifungal compounds;
D O I
10.1016/j.tetlet.2003.12.002
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel dinitro secondary metabolite, 2-nitro-4-(2'-nitroethenyl)phenol from a marine source, has been prepared via highly accelerated, microwave assisted, nitration reactions using mild reagents. ipso-substitution of a carboxy group by a nitro group is discussed. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1179 / 1181
页数:3
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