Atomically Thick Pt-Cu Nanosheets: Self-Assembled Sandwich and Nanoring-Like Structures

被引:107
作者
Saleem, Faisal [1 ]
Xu, Biao [1 ]
Ni, Bing [1 ]
Liu, Huiling [1 ]
Nosheen, Farhat [1 ]
Li, Haoyi [1 ]
Wang, Xun [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
atomically-thick nanosheets; Pt-Cu nanosheets; sandwich structures; self-assembly; formic acid oxidation; 2-DIMENSIONAL LAYERED NANOCRYSTALS; FORMIC-ACID DECOMPOSITION; CORE-SHELL NANOPARTICLES; PD; GRAPHENE; PALLADIUM; OXIDATION; CATALYST; GROWTH; CARBON;
D O I
10.1002/adma.201405319
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Atomically thick and flexible Pt-Cu alloy nanosheets are prepared and loaded with either Pd or Pt to produce sandwich structures or nanoring-like nanosheet structures, respectively. Core-shell alloy nanoparticles containing Rh, Ir, and Ru are also prepared. All of these structures exhibit superior specific and mass activities for the oxidation of formic acid for fuel cells for portable electronic devices as compared to commercial Pd/C catalyst.
引用
收藏
页码:2013 / 2018
页数:6
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