Transparent conductive Ga-doped ZnO/Cu multilayers prepared on polymer substrates at room temperature

被引:46
作者
Gong, Li [1 ,2 ]
Lu, Jianguo [1 ]
Ye, Zhizhen [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410015, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Zinc oxide; Multilayer; Magnetron sputtering; Transparent conductive oxides; Polycarbonate; OPTICAL-PROPERTIES; THIN-FILMS; DEPENDENCE; THICKNESS; GROWTH; ELECTRODE; PRESSURE; LAYERS;
D O I
10.1016/j.solmat.2011.02.004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In order to improve the transparency and durability of the Cu films deposited on polycarbonate (PC) substrates, a Ga-doped ZnO (GZO) layer could be deposited directly onto the Cu film. Compared with a single-layered GZO film, the GZO/Cu multilayer coatings have much lower sheet resistance and much thinner thickness. In our work, GZO/Cu multilayers were deposited by magnetron sputtering on PC substrates at room temperature. The structural, electrical, and optical properties of multilayers were investigated at various thicknesses of the Cu and GZO layers. As the Cu layer thickness increases, the resistivity decreases. As the GZO layer thickness increases, the resistivity increases. And we obtained that the transmittance of the GZO/Cu multilayer coatings was higher than that of the single Cu layer. The lowest resistivity of 5.7 x 10(-5) Omega cm with a carrier concentration of 3.25 x 10(22) cm(-3) was obtained at the optimum Cu (12 nm) and GZO (10 nm) layer thickness. The best figure of merit phi(TC) is 4.66 x 10(-3) Omega(-1) the GZO(30 nm)/Cu(12 nm) multilayer. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1826 / 1830
页数:5
相关论文
共 40 条
[21]   Development of multilayer transparent conductive coatings [J].
Leftheriotis, G ;
Papaefthimiou, S ;
Yianoulis, P .
SOLID STATE IONICS, 2000, 136 :655-661
[22]   Influence of annealing temperature on the properties of transparent conductive and near-infrared reflective ZnO:Ga films [J].
Ma, Quan-Bao ;
Ye, Zhi-Zhen ;
He, Hai-Ping ;
Zhu, Li-Ping ;
Huang, Jing-Yun ;
Zhang, Yin-Zhu ;
Zhao, Bing-Hui .
SCRIPTA MATERIALIA, 2008, 58 (01) :21-24
[23]   Effect of substrate temperature on structural, electrical and optical properties of Ga-doped ZnO films on cycro olefin polymer substrate by ion plating deposition [J].
Miyake, Aki ;
Yamada, Takahiro ;
Makino, Hisao ;
Yamamoto, Naoki ;
Yamamoto, Tetsuya .
THIN SOLID FILMS, 2008, 517 (03) :1037-1041
[24]   The low temperature process design for Al doped ZnO film synthesis on polymer [J].
Moon, Chang S. ;
Chung, Yun M. ;
Jung, Woo S. ;
Han, Jeon G. .
SURFACE & COATINGS TECHNOLOGY, 2007, 201 (9-11) :5035-5038
[25]   Moisture-resistant ZnO transparent conductive films with Ga heavy doping [J].
Nakagawara, Osamu ;
Kishimoto, Yutaka ;
Seto, Hiroyuki ;
Koshido, Yoshihiro ;
Yoshino, Yukio ;
Makino, Takahiro .
APPLIED PHYSICS LETTERS, 2006, 89 (09)
[26]   Characteristics of indium-free GZO/Ag/GZO and AZO/Ag/AZO multilayer electrode grown by dual target DC sputtering at room temperature for low-cost organic photovoltaics [J].
Park, Ho-Kyun ;
Kang, Jae-Wook ;
Na, Seok-In ;
Kim, Don-Yu ;
Kim, Han-Ki .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (11) :1994-2002
[27]   Room-Temperature Indium-Free Ga:ZnO/Ag/Ga:ZnO Multilayer Electrode for Organic Solar Cell Applications [J].
Park, Ho-Kyun ;
Jeong, Jin-A ;
Park, Yong-Seok ;
Na, Seok-In ;
Kim, Dong-Yu ;
Kim, Han-Ki .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2009, 12 (08) :H309-H311
[28]   Highly flexible indium zinc oxide electrode grown on PET substrate by cost efficient roll-to-roll sputtering process [J].
Park, Yong-Seok ;
Kim, Han-Ki ;
Jeong, Soon-Wook ;
Cho, Woon-Jo .
THIN SOLID FILMS, 2010, 518 (11) :3071-3074
[29]  
Pearson WB, 1972, CRYSTAL CHEM PHYS ME, P76
[30]   Highly oriented and conducting ZnO:Ga layers grown by chemical spray pyrolysis [J].
Reddy, KTR ;
Reddy, TBS ;
Forbes, I ;
Miles, RW .
SURFACE & COATINGS TECHNOLOGY, 2002, 151 (151-152) :110-113