Electrochemical and optical properties of a new donor-acceptor type conjugated polymer derived from 3,4-didodecyloxythiophene

被引：3

作者：

Hegde, Pramod Kumar ^{[1
]}

Adhikari, A. Vasudeva ^{[1
]}

Manjunatha, M. G. ^{[1
]}

机构：

[1] Natl Inst Technol, Dept Chem, Surathkal 575025, Srinivasnagar, India

来源：

BULLETIN OF MATERIALS SCIENCE | 2010年 / 33卷 / 06期

关键词：

Conjugated polymers; (1,3,4-oxadiazol-yl)pyridine; electrochemical properties; fluorescence; light emitting diodes; DEVICE;

D O I：

10.1007/s12034-011-0135-z

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this communication, we report the synthesis and characterization of a new donor acceptor type conjugated polymer carrying alternate 3,4-didodecyloxythiophene and (1,3,4-oxadiazol-yl)pyridine moieties and evaluation of its optical and electrochemical properties. The polymer was synthesized through precursor polyhydrazide route. It has well defined structure, stability and it shows good solubility in common organic solvents. Optical and electrochemical properties were studied by UV-visible, fluorescence spectroscopy and cyclic voltammetric studies, respectively. It displays bluish-green fluorescence both in solution and in film state. Cyclic voltammetric studies showed that the polymer P1 possesses a HOMO energy level of -6.01 and LUMO energy level of -3.34 eV. The preliminary studies clearly reveal that the new polymer can have potential application in the fabrication of light emitting diodes. The studies on its device application are in progress.

引用

页码：677 / 682

页数：6

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