Quintic equation of state for pure substances in sub- and supercritical range

被引：7
|
作者：
Koziol, Antoni [1 ]
机构：
[1] Wroclaw Univ Technol, Fac Chem, Div Chem & Biochem Proc, PL-50373 Wroclaw, Poland
来源：
FLUID PHASE EQUILIBRIA | 2008年 / 263卷 / 01期
关键词：
equation of state; vapour-liquid equilibria; polar and non-polar substances;
D O I：
10.1016/j.fluid.2007.09.012
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A new quintic equation of state (EOS) for pure substances and mixtures is proposed. The equation is based on critical parameters and one saturation point. The proposed Q5EOS is a generalisation of many cubic equations of state. Equation Q5 has five parameters, four of which are temperature-independent. The temperature-dependent parameter a is expressed by a relation based on a simple power function. Parameters defining this function can be calculated from saturation data, Boyle temperature and supercritical data. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：18 / 25
页数：8
相关论文
共 50 条
  • [31] Universal Scaling Form of the Equation of State of a Critical Pure Fluid
    Y. Garrabos
    B. Le Neindre
    R. Wunenburger
    C. Lecoutre-Chabot
    D. Beysens
    International Journal of Thermophysics, 2002, 23 : 997 - 1011
  • [32] Universal scaling form of the equation of state of a critical pure fluid
    Garrabos, Y
    Le Neindre, B
    Wunenburger, R
    Lecoutre-Chabot, C
    Beysens, D
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2002, 23 (04) : 997 - 1011
  • [33] The modified PGR equation of state: Pure-fluid predictions
    Row, KH
    Park, JK
    Gasem, KAM
    CHEMICAL ENGINEERING COMMUNICATIONS, 2006, 193 (04) : 438 - 459
  • [34] A new cubic equation of state for simple fluids: pure and mixture
    Nasrifar, K
    Moshfeghian, M
    FLUID PHASE EQUILIBRIA, 2001, 190 (1-2) : 73 - 88
  • [35] A wide-range multiphase equation of state for platinum
    Elkin, V. M.
    Mikhaylov, V. N.
    Ovechkin, A. A.
    Smirnov, N. A.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2020, 32 (43)
  • [36] Wide-range multiphase equation of state for iron
    A. B. Medvedev
    Combustion, Explosion, and Shock Waves, 2014, 50 : 582 - 598
  • [37] Wide-Range Multiphase Equation of State for Bismuth
    Medvedev, A. B.
    COMBUSTION EXPLOSION AND SHOCK WAVES, 2024, 60 (02) : 247 - 259
  • [38] A hard-sphere volume-translated van der Waals equation of state for supercritical process modeling .1. Pure components
    Kutney, MC
    Dodd, VS
    Smith, KA
    Herzog, HJ
    Tester, JW
    FLUID PHASE EQUILIBRIA, 1997, 128 (1-2) : 149 - 171
  • [39] Multiphase Wide-Range Equation of State for Copper
    V. M. El’kin
    V. N. Mikhailov
    A. A. Ovechkin
    Combustion, Explosion, and Shock Waves, 2024, 60 (6) : 770 - 780
  • [40] Wide-range multiphase equation of state for iron
    Medvedev, A. B.
    COMBUSTION EXPLOSION AND SHOCK WAVES, 2014, 50 (05) : 582 - 598
12345