Synthesis and Study of a Copper-Containing Nanostructured Catalyst for Dehydrogenation of Cyclohexanol into Cyclohexanone

被引:2
|
作者
Kon'kova, T. V. [1 ]
Vanchurin, V. I. [1 ]
Karachenko, O. I. [2 ]
Liberman, E. Yu. [1 ]
机构
[1] Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
[2] OAO Grodno Azot, Grodno 230013, BELARUS
关键词
nanostructured catalyst; copper hydroxocarbonate; cyclohexanol dehydrogenation;
D O I
10.1134/S1070427218080165
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The influence exerted by the synthesis conditions and composition of a copper-containing nanostructured catalyst for cyclohexanol dehydrogenation on its textural characteristics, activity, and thermal stability was studied. The content of copper in the hydroxocarbonate form and the textural characteristics of the catalyst increase with increasing temperature of the precursor deposition onto the support. The presence of aluminum oxide in the system enhances the thermal stability of the catalyst. High activity, selectivity, and thermal stability of the catalyst obtained allow recommending it for commercial production as an alternative to the imported catalyst.
引用
收藏
页码:1370 / 1374
页数:5
相关论文
共 50 条
  • [1] Synthesis and Study of a Copper-Containing Nanostructured Catalyst for Dehydrogenation of Cyclohexanol into Cyclohexanone
    T. V. Kon’kova
    V. I. Vanchurin
    O. I. Karachenko
    E. Yu. Liberman
    Russian Journal of Applied Chemistry, 2018, 91 : 1370 - 1374
  • [2] Characterization and Testing of Copper-Containing Catalysts in Dehydrogenation of Cyclohexanol into Cyclohexanone
    Vanchurin, V., I
    Karachenko, O., I
    Petrov, A. Yu
    Tarakanovskii, I., V
    Dzhumamukhamedov, D. Sh
    Pavlov, Yu L.
    Dul'nev, A., V
    CATALYSIS IN INDUSTRY, 2019, 11 (01) : 74 - 79
  • [3] Characterization and Testing of Copper-Containing Catalysts in Dehydrogenation of Cyclohexanol into Cyclohexanone
    V. I. Vanchurin
    O. I. Karachenko
    A. Yu. Petrov
    I. V. Tarakanovskii
    D. Sh. Dzhumamukhamedov
    Yu. L. Pavlov
    A. V. Dul’nev
    Catalysis in Industry, 2019, 11 : 74 - 79
  • [4] THE KINETICS OF THE DEHYDROGENATION OF CYCLOHEXANOL TO CYCLOHEXANONE ON A MODIFIED COPPER MAGNESIUM CATALYST
    ROVSKII, VA
    MEDVEDEVA, ON
    BELSKAYA, RI
    KOLTSOV, NI
    KIPERMAN, SL
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (03): : 366 - 368
  • [5] Dehydrogenation of cyclohexanol to cyclohexanone on Zn/Fe catalyst
    Zimowski, Andrzej
    Zylbersztejn, Michal
    Sylwestrowicz, Remigiusz
    PRZEMYSL CHEMICZNY, 2015, 94 (05): : 736 - 740
  • [6] Dehydrogenation of cyclohexanol on copper-containing catalysts -: II.: The pathways of the cyclohexanol dehydrogenation reaction to cyclohexanone on copper-active sites in oxidation state Cu0 and Cu+
    Fridman, VZ
    Davydov, AA
    Titievsky, K
    JOURNAL OF CATALYSIS, 2004, 222 (02) : 545 - 557
  • [7] KINETICS OF DEHYDROGENATION OF CYCLOHEXANOL TO CYCLOHEXANONE ON A BAG TYPE COPPER-ALLOY CATALYST
    ORIZARSKY, IV
    PETROV, LA
    PETROVA, VM
    REACTION KINETICS AND CATALYSIS LETTERS, 1981, 17 (3-4): : 427 - 431
  • [8] Study of the deactivation of copper-based catalysts for dehydrogenation of cyclohexanol to cyclohexanone
    Simon, Ernesto
    Maria Rosas, Juana
    Santos, Aurora
    Romero, Arturo
    CATALYSIS TODAY, 2012, 187 (01) : 150 - 158
  • [10] CuO-ZnO-MgO as sustainable and selective catalyst towards synthesis of cyclohexanone by dehydrogenation of cyclohexanol over monovalent copper
    Sancheti, Sonam, V
    Yadav, Ganapati D.
    MOLECULAR CATALYSIS, 2021, 506