Sequential Production of Xylose, Levulinic Acid and Activated Carbon from Pine Wood

被引:3
作者
Kang, Shimin [1 ,2 ]
Lai, Wenkang [1 ,2 ]
Yin, Xiaodong [1 ,2 ]
Peng, Zhezhe [1 ,2 ]
Tu, Junling [1 ,2 ]
Huang, Si-Min [1 ,2 ]
机构
[1] Dongguan Univ Technol, Guangdong Prov Key Lab Distributed Energy Syst, Dongguan, Guangdong, Peoples R China
[2] Dongguan Univ Technol, Engn Res Ctr None Food Biomass Efficient Pyrolysi, Guangdong Higher Educ Inst, Donguan, Peoples R China
来源
CHEMISTRYSELECT | 2018年 / 3卷 / 34期
基金
中国国家自然科学基金;
关键词
activated carbon; adsorption; biomass; levulinic acid; lignocellulosic biomass; xylose; CATALYTIC CONVERSION; ADSORPTION; BIOMASS; LIGNIN; HYDROLYSIS; CELLULOSE; PLATFORM; GLUCOSE; FUELS; DYE;
D O I
10.1002/slct.201802075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, a sequential production of bioenergy platform intermediates (i.e., xylose and levulinic acid (LA)) and carbon materials from pine wood was developed by a three-step conversion technology. Firstly, the hemicellulose in pine wood was hydrolyzed, obtaining 12.8 wt% xylose and 68.9 wt% solid products containing cellulose and lignin. Secondly, the solid products were hydrolyzed, obtaining 30.6 wt% LA and 42.0 wt % solid residues containing humins and lignin. Thirdly, the solid residues were used for activated carbon (AC) production through potassium hydrate (KOH) activation followed by pyrolysis from 400-800 degrees C. An AC obtained at a pyrolysis temperature of 800 degrees C had a high Brunauer-Emmett-Teller (BET) surface area of 2436 m(2)/g and pore volume of 0.91 cm(1)/g, which exhibited an excellent reactive brilliant red X-3B (RBRX3B) adsorption capacity of 892 mg/g. As a case, 1000 g of pine wood finally produced 128 g xylose, 211 g LA and 39 g highperformance activated carbon.
引用
收藏
页码:9819 / 9825
页数:7
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