Highly efficient phthalocyanine based aqueous Zn-ion flexible-batteries

被引：10

作者：

Hwang, Byungil ^{[1
]}

Cheong, Jun Young ^{[2
,5
]}

Matteini, Paolo ^{[3
]}

Yun, Tae Gwang ^{[4
]}

机构：

[1] Chung Ang Univ, Sch Integrat Engn, Seoul 06974, South Korea

[2] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Daejeon 34141, South Korea

[3] Inst Appl Phys Nello Carrara, Natl Res Council, Via Madonna Piano 10, I-50019 Sesto Fiorentino, Italy

[4] Myongji Univ, Dept Mat Sci & Engn, Yongin 17058, Gyeonggi, South Korea

[5] Samsung SDI, 467 Beonyeong Ro, Cheonan 31086, South Korea

来源：

MATERIALS LETTERS | 2022年 / 306卷

基金：

新加坡国家研究基金会;

关键词：

Aqueous Zn-ion batteries; Electrochemical reliability; Phthalocyanine; Intercalation; de-intercalation reaction; CHALLENGES;

D O I：

10.1016/j.matlet.2021.130954

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Aqueous Zn-ion battery has developed as an alternative to overcome the limitations of conventional Li-ion batteries, but its application is insufficient due to low reversibility and electrochemical reliability. In this study, we developed a cathode for aqueous Zn-ion battery with improvement of reversibility and electrochemical reliability utilizing phthalocyanine (PTC) that efficiently transports metal ions and electrons. The intercalation/ de-intercalation reaction of Zn2+ ions changes according to the central metal ligand ion of PTC, and iron (II) coordinated PTC exhibited the outstanding energy storage capacity (161.34 mAh/g) and electrochemical reliability (99%, 100 cycles). Based on maximized electrochemical performance and reliability, Zn-ion flexible battery was successfully demonstrated by utilizing air-spray coating.

引用

页数：4

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