Synthesis of a selenium-substituted diselenide

被引：10

作者：

Cox, M ^{[1
]}

Wirth, T ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2005年 / 180卷 / 3-4期

关键词：

diselenides; selenium electrophiles; stereoselective synthesis;

D O I：

10.1080/10426500590907282

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A wide range of diselenides as precursors for selenium electrophiles is already known, but the development of reagents with higher selectivity is still ongoing. Herein we report the first synthesis of selenium-stabilized diselenides together with some preliminary reactions of, these reagents in stereoselective selenenylation reactions.

引用

页码：659 / 666

页数：8

共 19 条

[1] [Anonymous], 2000, ANGEW CHEM-GER EDIT
[2] Back T. G., 1999, ORGANOSELENIUM CHEM
[3] COX M, 2004, THESIS CARDIFF U
[4] Characterization of an intramolecular nonbonded interaction between selenium and fluorine in solution
Iwaoka, M
Komatsu, H
Tomoda, S
[J]. CHEMISTRY LETTERS, 1998, (10) : 969 - 970
[5] Intramolecular non-bonded interaction between selenium and oxygen as revealed by 17O and 77Se NMR spectroscopy and natural bond orbital analysis
Komatsu, H
Iwaoka, M
Tomoda, S
[J]. CHEMICAL COMMUNICATIONS, 1999, (02) : 205 - 206
[6] Theoretical investigations on the stereoselective selenenylation reaction of alkenes
Spichty, M
Fragale, G
Wirth, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (44) : 10914 - 10916
[7] Tiecco M, 2000, TOP CURR CHEM, V208, P7
[8] Tiecco M, 2002, CHEM-EUR J, V8, P1118, DOI 10.1002/1521-3765(20020301)8:5<1118::AID-CHEM1118>3.0.CO
[9] 2-2
[10] A sulfur-containing diselenide as an efficient chiral reagent in asymmetric selenocyclization reactions
Tiecco, M
Testaferri, L
Marini, F
Sternativo, S
Bagnoli, L
Santi, C
Temperini, A
[J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (10) : 1493 - 1502

← 1 2 →