MnOx-CeO2 catalysts for effective NOx reduction in the presence of chlorobenzene

被引：64
作者：
Gan, Lina [1 ]
Li, Kezhi [1 ]
Xiong, Shangchao [1 ]
Zhang, Yani [1 ]
Chen, Jianjun [1 ]
Peng, Yue [1 ]
Li, Junhua [1 ]
机构：
[1] Tsinghua Univ, State Key Joint Lab Environm Simulat & Pollut Con, Sch Environm, Beijing 100084, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2018年 / 117卷
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
NH3-SCR; Chlorobenzene; Synergy; MnOx-CeO2; TOTAL OXIDATION; OXIDE; NH3; COMBUSTION; PERFORMANCES; MECHANISM; PROMOTION; ABATEMENT; AMMONIA; PCDD/FS;
D O I：
10.1016/j.catcom.2018.08.008
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic performance of MnOx-CeO2 for the simultaneous NOx reduction and chlorobenzene (CB) oxidation was investigated. The MnOx(0.4)-CeO2 solid composition exhibited excellent catalytic activity due to the formation of MnyCe1-yO2-delta solid solution and the good balance between redox properties and surface acidity compared to pure ceria. The presence of CB improved both the NOx conversion and N-2 selectivity in the range of 200-300 degrees C. Furthermore, the activity temperature window for NOx reduction was broadened when CB was introduced into the flue gas, and the CB oxidation ability was also enhanced in the presence of O-2 and NH3/NO.
引用
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页码：1 / 4
页数：4
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