Metal-assisted electrocyclic reaction in a C=N-N=C-C=N system

被引：26

作者：

Pal, PK

Chowdhury, S

Drew, MGB

Datta, D ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

NEW JOURNAL OF CHEMISTRY | 2000年 / 24卷 / 12期

关键词：

D O I：

10.1039/b006547l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a reaction with cis-Ru(phen)(2)Cl-2, the 1:2 condensate of benzil dihydrazone and 2-formylpyridine or 2-acetylpyridine is found to undergo an electrocyclic rearrangement to yield the cation (Ru(phen)(2){5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine}](2+), which has been isolated as its hexafluorophosphate salt and characterised by X-ray crystallography.

引用

页码：931 / 933

页数：3

共 11 条

[1] 6-COORDINATE COMPLEXES WITH 1,10-PHENANTHROLINE LIGANDS IN THE TRANS CONFIGURATION - PREPARATION OF TRANS-BIS(1,10-PHENANTHROLINE)RUTHENIUM(II) COMPLEXES AND CRYSTAL-STRUCTURE OF TRANS-BIS(1,10-PHENANTHROLINE)BIS(PYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE [J].