Selective 1,2 addition of polar X-H bonds to the Ga-P double bond of gallaphosphene L(Cl) GaPGaL

被引：18
作者：
Sharma, Mahendra K.
Wolper, Christoph
Schulz, Stephan [1 ]
机构：
[1] Univ Duisburg Essen, Inst Inorgan Chem, Univ Str 5-7, D-45141 Essen, Germany
来源：
DALTON TRANSACTIONS | 2022年 / 51卷 / 04期
关键词：
MAIN-GROUP ELEMENTS; DISILYNE RSISIR R; MONOMERIC IMIDES; SINGLE-BOND; GALLIUM; ACTIVATION; DIGERMYNE; HYDROGEN; H-2; REACTIVITY;
D O I：
10.1039/d1dt04299h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Gallaphosphene L(Cl)GaPGaL 1 (L = HC[C(Me)N(2,6-i-Pr-2-C6H3)](2)) reacts at ambient temperature with a series of polar X-H bonds, i.e. ammonia, primary amines, water, phenol, thiophenol, and selenophenol, selectively with 1,2 addition at the polar Ga-P double bond. The gallium atom serves as electrophile and the phosphorous atom is protonated in all reactions. The resulting complexes L(Cl)GaP(H)Ga(X)L (X = NH2 2, NHi-Pr 3, NHPh 4, OH 5, OXyl 6, SPh 7, SePh 8) were characterized by IR and heteronuclear (H-1, C-13 {H-1}, P-31{H-1}) NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.
引用
收藏
页码：1612 / 1616
页数：5
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