Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

被引：101

作者：

Chen, Man-Sheng ^{[1
,2
]}

Chen, Min ^{[1
]}

Takamizawa, Satoshi ^{[3
]}

Okamura, Taka-aki ^{[4
]}

Fan, Jian ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China

[2] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China

[3] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, Kanagawa 2360027, Japan

[4] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka 5600043, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; CO2; POLYMER;

D O I：

10.1039/c0cc04689b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC-SC fashion, and shows selective adsorption of H-2 and CO2 over N-2.

引用

收藏

页码：3787 / 3789

页数：3

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