Slow Magnetic Relaxation in Novel Dy4 and Dy8 Compounds

被引：86
|
作者：
Yang, Pei-Pei [1 ,2 ]
Gao, Xi-Feng [1 ,2 ]
Song, Hai-Bin [3 ]
Zhang, Sai [1 ,2 ]
Mei, Xue-Lan [1 ,2 ]
Li, Li-Cun [1 ,2 ]
Liao, Dai-Zheng [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
[3] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 03期
基金：
中国国家自然科学基金;
关键词：
SINGLE-MOLECULE MAGNETS; ANISOTROPIC BARRIER; HIGH-SPIN; BEHAVIOR; CLUSTER; NANOMAGNETS; COBALT(II); AGGREGATE; TRIANGLES; CRYSTAL;
D O I：
10.1021/ic1021643
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel dysprosium(III) clusters have been prepared and structurally characterized. One has a tetranuclear core with a rare zigzag arrangement, and the other is an unprecedented octanuclear cluster with six triangular Dy-3 units sharing vertices. Both dysprosium(III) clusters possess frequency-dependent on alternating-current magnetic susceptibilities, indicating possible single-molecule magnet behavior.
引用
收藏
页码：720 / 722
页数：3
相关论文
共 50 条
  • [21] Asymmetric {Dy4} metallogrid and double-layered {Dy8} cage clusters from carboxylic decorated o-vanillin Schiff bases: syntheses, topological variation, and single molecule magnet behaviors
    Wang, Yi-Han
    Qin, Yu
    Tang, Shen
    Teng, Qing-Hu
    Zhu, Meng-Meng
    Peng, Song
    Wang, Kai
    Liang, Fu-Pei
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (04) : 2052 - 2059
  • [22] A triacontanuclear [Zn12Dy18] cluster: a ring of [Dy4] cubes
    Stavgianoudaki, Nikoleta
    Siczek, Milosz
    Lis, Tadeusz
    Inglis, Ross
    Milios, Constantinos J.
    CHEMICAL COMMUNICATIONS, 2016, 52 (02) : 343 - 345
  • [23] Slow magnetic relaxation in a novel heptanuclear Dy7 cluster with five edge-sharing Dy3 triangles
    Guo, Fu-Sheng
    Guo, Peng-Hu
    Meng, Zhao-Sha
    Tong, Ming-Liang
    POLYHEDRON, 2011, 30 (18) : 3079 - 3082
  • [24] Two Ln(III)2 (Ln = Gd and Dy) compounds showing magnetic refrigeration and slow magnetic relaxation
    Shi, Xiao-Hong
    Hao, Sha-Sha
    Wang, Mei-Jiao
    Zhang, Lin
    Liang, Wen-Hui
    Gao, Hui-Min
    Wang, Jie
    Shi, Ying
    Wang, Wen-Min
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1210
  • [25] A series of tetranuclear lanthanide complexes comprising two edge-sharing triangular units with field-induced slow magnetic relaxation for Dy4 species
    Xue, Shufang
    Zhao, Lang
    Guo, Yun-Nan
    Deng, Ruiping
    Guo, Yang
    Tang, Jinkui
    DALTON TRANSACTIONS, 2011, 40 (33) : 8347 - 8352
  • [26] Slow magnetic relaxation in distorted tetrahedral Dy(iii) aryloxide complexes
    Parmar, Vijay S.
    Gransbury, Gemma K.
    Whitehead, George F. S.
    Mills, David P.
    Winpenny, Richard E. P.
    CHEMICAL COMMUNICATIONS, 2021, 57 (73) : 9208 - 9211
  • [27] Dysprosium thiosilicate, Dy4(SiS4)3
    Hatscher, ST
    Urland, W
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : I74 - I75
  • [28] Coupling Dy3 Triangles Enhances Their Slow Magnetic Relaxation
    Hewitt, Ian J.
    Tang, Jinkui
    Madhu, N. T.
    Anson, Christopher E.
    Lan, Yanhua
    Luzon, Javier
    Etienne, Mael
    Sessoli, Roberta
    Powell, Annie K.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (36) : 6352 - 6356
  • [29] Two New One-Dimensional Homospin Dy(III) Compounds Showing Slow Magnetic Relaxation
    Luo, Feng
    Song, Yu-Mei
    Huang, Hai-Xiao
    Tian, Xiao-Zhao
    Sun, Gong-Ming
    Zhu, Yan
    Feng, Xue-Feng
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2012, 65 (10) : 1436 - 1442
  • [30] A novel Dy4III cluster constructed by a multidentate 8-hydroxyquinoline Schiff base ligand: Structure and slow magnetic relaxation behavior
    Hou, Yin-Ling
    Liu, Lan
    Hou, Zi-Ting
    Sheng, Cai-Yan
    Wang, Dang-Tong
    Jia, Jia
    Shi, Ying
    Wang, Wen-Min
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 112
12345