A new oxo-bridged borate derived from dimeric boron complexes

被引：10
|
作者：
Barba, V [1 ]
Vargas, G [1 ]
Gómez, E [1 ]
Farfán, N [1 ]
机构：
[1] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico
来源：
INORGANICA CHIMICA ACTA | 2000年 / 311卷 / 1-2期
关键词：
boron complexes; tridentate ligands; dimeric complexes; oxo-bridged complexes;
D O I：
10.1016/S0020-1693(00)00282-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of 2-salicylideneamino hydroxyethane (H(2)SAE) with B(NMe2)(3), B(OH)(3) and C6F5B(OH)(2) leads to the dimeric boron compounds [B(SAE)(NMe2)](2) (2), [B(SAE)(OH)](2) (3) and [B(SAE)(C6F5)](2) (4) in moderate to good yields. Compound 2 hydrolyses slowly at room temperature (r.t.) to give the dimeric ore-bridged boron compound mu -oxo-[B(SAE)](2) (5). Dehydration of 3 or hydrolysis of 4 with elimination of the aryl group conduced to the same derivative. The X-ray crystallographic analysis confirmed the molecular structure for compound 5. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：133 / 137
页数：5
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