Bis[μ-4-(dimethylamino)benzoato]-κ3O,O′:O;κ3O:O,O′-bis{aqua[4-(dimethylamino)benzoato-κ2O,O′](nicotinamide-κN1)cadmium(II)}

被引：6

作者：

Hokelek, Tuncer ^{[1
]}

Suzen, Yasemin ^{[2
]}

Tercan, Baris ^{[3
]}

Aybirdi, Oezguer ^{[4
]}

Necefoglu, Hacali ^{[4
]}

机构：

[1] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey

[2] Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Yenibaglar, Eskisehir, Turkey

[3] Karabuk Univ, Dept Phys, TR-78050 Karabuk, Turkey

[4] Kafkas Univ, Dept Chem, TR-63100 Kars, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

MAGNETIC-PROPERTIES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; MONOHYDRATE; CARBOXYLATE; COMPLEXES; DIHYDRATE;

D O I：

10.1107/S160053681002163X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric dimeric CdII title compound, [Cd 2(C9H10NO2)4(C 6H6N2O)2(H2O) 2], each seven-coordin-ated CdII atom is chelated by the carboxylate groups of the two 4-(dimethylamino)-benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π contacts between the pyridine rings [centroid-centroid distance = 3.974 (1) Å] may further stabilize the structure. Weak C-H⋯π inter-actions are also observed.

引用

页码：M782 / U623

页数：13

共 22 条

[1] COBALT DIHYDROGEN DIPHTHALATE HEXAHYDRATE [J].

ADIWIDJAJA, G ;

ROSSMANITH, E ;

KUPPERS, H .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (OCT) :3079-3083

[2]

AMIRASLANOV IR, 1979, ZH STRUKT KHIM, V20, P1075

[3]

[Anonymous], 2005, SADABS

[4] SYNTHESIS AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF MIXED-LIGAND COMPLEXES OF COPPER(II) WITH IMIDAZOLE AND N-PROTECTED AMINO-ACIDS - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(HIPPURATO)BIS(IMIDAZOLE)COPPER(II) [J].

ANTOLINI, L ;

BATTAGLIA, LP ;

CORRADI, AB ;

MARCOTRIGIANO, G ;

MENABUE, L ;

PELLACANI, GC ;

SALADINI, M .

INORGANIC CHEMISTRY, 1982, 21 (04) :1391-1395

[5]

ANTSYSHKINA AS, 1980, KOORDINATS KHIM, V15, P1098

[6] CRYSTAL AND MOLECULAR STRUCTURE OF MONO-(N,N-DIETHYLNICOTINAMIDE)CADMIUM DITHIOCIOCYANATE [J].

BIGOLI, F ;

BRAIBANTI, A ;

TIRIPICCHIO, A ;

PELLINGHELLI, MA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAR15) :962-+

[7]

Bruker, 2007, APEX2 SAINT

[8] PREPARATION, X-RAY CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF A TRINUCLEAR COBALT(II) CARBOXYLATE [J].

CATTERIC.J ;

HURSTHOUSE, MB ;

NEW, DB ;

THORNTON, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (20) :843-844

[9] Crystal structures of two- and three-dimensional polymeric complexes assembled by metal pseudohalides and 4-aminobenzoic acid via hydrogen bonds and covalent bonds [J].

Chen, HJ ;

Chen, XM .

INORGANICA CHIMICA ACTA, 2002, 329 (01) :13-21

[10]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

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