Controlled synthesis of LaPO4 and CePO4 nanorods/nanowires

被引:97
作者
Cao, MH [1 ]
Hu, CW
Wu, QY
Guo, CX
Qi, YJ
Wang, EB
机构
[1] NE Normal Univ, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China
[2] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China
[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
关键词
D O I
10.1088/0957-4484/16/2/018
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
LaPO4 and CePO4 nanorods/nanowires with controlled aspect ratios have been successfully synthesized using a hydrothermal microemulsion method under mild conditions. It has been shown that the obtained LaPO4 has a monoclinic structure, while CePO4 exists in the hexagonal structure. Uniform nanorods/nanowires with diameters of 20-60 nm and lengths ranging from several hundreds of nanometres to several micrometres were obtained. The aspect ratios of the obtained 1 D nanostructures can be fine-tuned by simply changing the [H2O]/[surfactant] molar ratios. The possible growth mechanism of LaPO4 and CePO4 nanorods/nanowires was explored in detail.
引用
收藏
页码:282 / 286
页数:5
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共 34 条
[1]   The binary rare earth oxides [J].
Adachi, G ;
Imanaka, N .
CHEMICAL REVIEWS, 1998, 98 (04) :1479-1514
[2]   Doped nanocrystalline materials - Physics and applications [J].
Bhargava, RN .
JOURNAL OF LUMINESCENCE, 1996, 70 :85-94
[3]   The first fluoride one-dimensional nanostructures:: Microemulsion-mediated hydrothermal synthesis of BaF2 whiskers [J].
Cao, MH ;
Hu, CW ;
Wang, EB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11196-11197
[4]   Optical spectroscopy and upconversion studies of Ho3+-doped bulk and nanocrystalline Y2O3 [J].
Capobianco, JA ;
Boyer, JC ;
Vetrone, F ;
Speghini, A ;
Bettinelli, M .
CHEMISTRY OF MATERIALS, 2002, 14 (07) :2915-2921
[5]   INTERDROPLET EXCHANGE-RATES OF WATER-IN-OIL AND OIL-IN-WATER MICROEMULSION DROPLETS STABILIZED BY C12E5 [J].
CLARK, S ;
FLETCHER, PDI ;
YE, XL .
LANGMUIR, 1990, 6 (07) :1301-1309
[6]   Synthesis and magnetic properties of nickel nanorods [J].
Cordente, N ;
Respaud, M ;
Senocq, F ;
Casanove, MJ ;
Amiens, C ;
Chaudret, B .
NANO LETTERS, 2001, 1 (10) :565-568
[7]   Photoluminescence characteristics of Y2O3:Eu3+ nanophosphors prepared using sol-gel thermolysis [J].
Dhanaraj, J ;
Jagannathan, R ;
Kutty, TRN ;
Lu, CH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (45) :11098-11105
[8]   Systematic synthesis and characterization of single-crystal lanthanide orthophosphate nanowires [J].
Fang, YP ;
Xu, AW ;
Song, RQ ;
Zhang, HX ;
You, LP ;
Yu, JC ;
Liu, HQ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :16025-16034
[9]   Blue, green, and red upconversion emission from lanthanide-doped LuPO4 and YbPO4 nanocrystals in a transparent colloidal solution [J].
Heer, S ;
Lehmann, O ;
Haase, M ;
Güdel, HU .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (27) :3179-3182
[10]   Synthesis of barium sulfate nanoparticles and nanofilaments in reverse micelles and microemulsions [J].
Hopwood, JD ;
Mann, S .
CHEMISTRY OF MATERIALS, 1997, 9 (08) :1819-1828