Surfactant-assisted titanium dioxide/graphene composite for enhanced conductivity

被引:13
作者
Liu, Lin [1 ]
Li, Ying [1 ]
E, Tao [1 ]
Jiang, Zhigang [2 ]
Yang, Shuyi [1 ]
Xu, Jiasheng [1 ]
Qian, Jianhua [1 ]
机构
[1] Bohai Univ, Coll Chem & Chem Engn, Liaoning Prov Key Lab Synth & Applicat Funct Cpds, Jinzhou 121013, Liaoning, Peoples R China
[2] Jinzhou Titanium Ind Co Ltd, Jinzhou 121013, Liaoning, Peoples R China
关键词
Graphene; TiO2; Conductivity; Dispersibility; GRAPHENE OXIDE NANOCOMPOSITES; LITHIUM-ION BATTERIES; PHOTOCATALYTIC ACTIVITY; HYDROTHERMAL SYNTHESIS; TIO2; PERFORMANCES; NANOPARTICLE; NANOFIBERS; NANOWIRES;
D O I
10.1016/j.matchemphys.2018.05.075
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Titanium dioxide/graphene (TiO2/G) was synthesized by a simple method through adding cationic surfactant to assist the stabilization of rutile TiO2 in aqueous solutions and facilitate the electrostatic assembly of binding with surface of graphene. TiO2/G materials were used for investigation of its conductivity and dispersibility. The TiO2/G was showed significantly to enhance in conductivity and dispersibility after adding cetyl-trimethylammonium bromide (CTAB). The good performance may be attributed to increasing TiO 2 to uniformly distribute on the surface of graphene in the presence of CTAB. The TiO2/G composite was characterized by Zeta potential, Fourier transformed infrared spectra (IR), X-ray diffraction (XRD), Scanning electron microscopy (SEM) and Electrochemical impedance spectroscopy (EIS), respectively. The CTAB does not affect the crystalline structure of TiO2 and graphene. When CTAB is 30%wt of TiO2 and graphene is 7%wt of TiO2 that the resistivity of TiO2/G is measured as 2.4 & nbsp;Omega cm. The dispersion of TiO2/G can be kept for 24 h without precipitation. EIS showed that the TiO2/G with 30%wt of CTAB had the lowest electrical resistance, which tended to be consistent with the results of the measured resistivity. The results showed that the best conductivity and dispersibility of the TiO2/G composite with CTAB in this experiment.
引用
收藏
页码:365 / 370
页数:6
相关论文
共 30 条
[1]  
Ahmmad B, 2014, WASET, V8, P24
[2]   Electrochemical Synthesis and In Situ Spectroelectrochemistry of Conducting Polymer Nanocomposites. I. Polyaniline/TiO2, Polyaniline/ZnO, and Polyaniline/TiO2+ZnO [J].
Arjomandi, Jalal ;
Tadayyonfar, Sahar .
POLYMER COMPOSITES, 2014, 35 (02) :351-363
[3]   Ultrahigh electron mobility in suspended graphene [J].
Bolotin, K. I. ;
Sikes, K. J. ;
Jiang, Z. ;
Klima, M. ;
Fudenberg, G. ;
Hone, J. ;
Kim, P. ;
Stormer, H. L. .
SOLID STATE COMMUNICATIONS, 2008, 146 (9-10) :351-355
[4]   Synthesis and characterization of TiO2 pillared montmorillonites: Application for methylene blue degradation [J].
Chen, Daimei ;
Du, Gaoxiang ;
Zhu, Qian ;
Zhou, Fengsan .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2013, 409 :151-157
[5]   Recent advances in nanomaterials for water protection and monitoring [J].
Das, Rasel ;
Vecitis, Chad D. ;
Schulze, Agnes ;
Cao, Bin ;
Ismail, Ahmad Fauzi ;
Lu, Xianbo ;
Chen, Jiping ;
Ramakrishna, Seeram .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (22) :6946-7020
[6]   Facile synthesis of graphene supported ultralong TiO2 nanofibers from the commercial titania for high performance lithium-ion batteries [J].
Gu, Guifang ;
Cheng, Jianli ;
Li, Xiaodong ;
Ni, Wei ;
Guan, Qun ;
Qu, Guoxing ;
Wang, Bin .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (12) :6642-6648
[7]   Solvothermal fabrication of three-dimensionally sphere-stacking Sb-SnO2 electrode based on TiO2 nanotube arrays [J].
Guo, Yan ;
Duan, Tigang ;
Chen, Ye ;
Wen, Qing .
CERAMICS INTERNATIONAL, 2015, 41 (07) :8723-8729
[8]   Graphene sheets anchored with high density TiO2 nanocrystals and their application in quantum dot-sensitized solar cells [J].
He, Jinjin ;
Wu, Dapeng ;
Gao, Zhiyong ;
Xu, Fang ;
Jiang, Shiwei ;
Zhang, Shuo ;
Cao, Kun ;
Guo, Yuming ;
Jiang, Kai .
RSC ADVANCES, 2014, 4 (04) :2068-2072
[9]  
Hong B.H., 2009, NATURE, V457, P706
[10]   Synthesis of TiO2 nanowire/reduced graphene oxide nanocomposites and their photocatalytic performances [J].
Hu, Ju ;
Li, Hansheng ;
Wu, Qin ;
Zhao, Yun ;
Jiao, Qingze .
CHEMICAL ENGINEERING JOURNAL, 2015, 263 :144-150