Communication-Imidazole Based Magnesium Salt as Conductive Salt for Rechargeable Magnesium-Ion Batteries

被引:5
作者
Zoidl, Manuel [1 ]
God, Colin [1 ]
Handel, Patricia [1 ]
Fischer, Roland [3 ]
Lenardt, Christian [1 ]
Schmuck, Martin [1 ]
Wrodnigg, Tanja M. [2 ]
机构
[1] VARTA Micro Innovat GmbH, A-8010 Graz, Austria
[2] Graz Univ Technol, Inst Organ Chem, Glycogrp, A-8010 Graz, Austria
[3] Graz Univ Technol, Inst Inorgan Chem, A-8010 Graz, Austria
关键词
ELECTROLYTES; LITDI;
D O I
10.1149/2.0101613jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this work we describe the synthesis and electrochemical evaluation of a novel imidazole based magnesium-Huckel salt as electrolyte system for rechargeable magnesium-ion batteries. This conductive salt, when applied in organic, aprotic solvents, enables both, the use of metallic magnesium as well as insertion materials as negative electrodes for rechargeable magnesium-ion batteries. (C) 2016 The Electrochemical Society. All rights reserved.
引用
收藏
页码:A2461 / A2463
页数:3
相关论文
共 17 条
[1]   Novel weakly coordinating heterocyclic anions for use in lithium batteries [J].
Armand, Michel ;
Johansson, Patrik .
JOURNAL OF POWER SOURCES, 2008, 178 (02) :821-825
[2]   A Key concept in Magnesium Secondary Battery Electrolytes [J].
Bertasi, Federico ;
Hettige, Chaminda ;
Sepehr, Fatemeh ;
Bogle, Xavier ;
Pagot, Gioele ;
Vezzu, Keti ;
Negro, Enrico ;
Paddison, Stephen J. ;
Greenbaum, Steve G. ;
Vittadello, Michele ;
Di Noto, Vito .
CHEMSUSCHEM, 2015, 8 (18) :3069-3076
[3]   Confession of a Magnesium Battery [J].
Bucur, Claudiu B. ;
Gregory, Thomas ;
Oliver, Allen G. ;
Muldoon, John .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (18) :3578-3591
[4]  
Handel P., 2015, ECS T, V66, P127
[5]   Operating mechanisms of electrolytes in magnesium ion batteries: chemical equilibrium, magnesium deposition, and electrolyte oxidation [J].
Kim, Dong Young ;
Lim, Younhee ;
Roy, Basab ;
Ryu, Young-Gyoon ;
Lee, Seok-Soo .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (47) :25789-25798
[6]  
Koller S., 2015, Patent No. [WO2015/090897 A1, 2015090897]
[7]   A Scientific Study of Current Collectors for Mg Batteries in Mg(AlCl2EtBu)2/THF Electrolyte [J].
Lv, Dongping ;
Xu, Terrence ;
Saha, Partha ;
Datta, Moni Kanchan ;
Gordin, Mikhail L. ;
Manivannan, Ayyakkannu ;
Kumta, Prashant N. ;
Wang, Donghai .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (02) :A351-A355
[8]  
Mothtadi R., 2014, BEILSTEIN J NANOTECH, V5, P1291
[9]   LiTDI and solvent mixture based electrolytes for lithium-ion cells [J].
Niedzicki, L. ;
Brzozowski, B. ;
Wieczorek, P. .
ELECTROCHIMICA ACTA, 2015, 174 :625-629
[10]   Liquid electrolytes based on new lithium conductive imidazole salts [J].
Niedzicki, L. ;
Kasprzyk, M. ;
Kuziak, K. ;
Zukowska, G. Z. ;
Marcinek, M. ;
Wieczorek, W. ;
Armand, M. .
JOURNAL OF POWER SOURCES, 2011, 196 (03) :1386-1391