Chiral recognition of carboxylic acids by chiral nitrogen containing calix[4]arene

被引：6
|
作者：
Zheng, YS [1 ]
Xiao, Q [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2005年 / 23卷 / 10期
关键词：
chiral nitrogen-containing calix[4]arene; chiral recognition; carboxylic acid;
D O I：
10.1002/cjoc.200591289
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral nitrogen-containing calix[4]arene was easily synthesized by the reaction of 25,27-di(2-bromoethoxy)26,28-dihydroxy-5,11,17,23-tetrakis(t-butyl)calix[4]arene with S-(-)-1-phenylethylaniine in excellent yield, and showed good ability to recognize the enantiomers of mandelic acid and 2,3-dibenzoyltartaric acid. This finding has potential application to assay and separation of enantiorners of the carboxylic acids.
引用
收藏
页码：1289 / 1291
页数：3
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